Island Water Assoc., Inc. Reverse Osmosis Plant - Executive Summary

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ISLAND WATER ASSOCIATION REVERSE OSMOSIS TREATMENT FACILITY 
 
EXECUTIVE SUMMARY 
 
The Island Water Association Reverse Osmosis Plant (Facility) provides potable water to the 
residents of Sanibel and Captiva Islands for drinking and fire fighting.  The Facility also removes 
Hydrogen Sulfide (H2S), salt and other substances from the brackish water prior to distribution.  The 
Facility uses one regulated substance, chlorine (CAS 7782-50-5) as a disinfectant to treat potable 
water during the chlorination processes.  To accomplish this goal, raw water is pumped from deep 
brackish wells to the facility. Upon entering the Facility, the raw water is chemically treated, filtered 
and passed into the Reverse Osmosis (RO) treatment system where the salt is removed and the water 
is divided into two components.  The first component is composed of concentrated salt water (brine) 
and H2S, which must undergo further treatment prior to being discharged into the Gulf of Mexico.  
The second component is ref 
erred to as "permeate" or "product water" which will be treated further 
(post-treated permeate) before being distributed to Facility customers. The Facility also uses chlorine 
in the sulfide conversion system to eliminate H2S from the permeate.  Once sulfide conversion has 
been accomplished, additional chlorine is added to the treated permeate to allow for adequate 
disinfection. The brine effluent from the RO process is also chlorinated in order to remove hydrogen 
sulfide.  It is then aerated to add oxygen and remove any trace H2S before being discharged into the 
Gulf of Mexico. 
 
While the chlorination systems at the Facility used for removing H2S, disinfecting the permeate and 
treating brine are comprised of separate systems, the technology and equipment utilized are the 
same. The chlorination processes at the facility are operated under a vacuum which is created by the 
ejectors.  In the chlorination processes, chlorine gas is pulled from the supply cylinders into 
chlorinators.  From  
the chlorinators, the chlorine gas flows to the ejectors that mix the chlorine gas 
with a side stream of pre-treated permeate to form a high concentration (approximately 500 parts per 
million (ppm)) chlorine solution. The chlorine solution then flows into each stream to be treated. 
 
The Facility performed a Process Hazard Analysis (PHA) to address the hazards in the chlorination 
processes and to evaluate and control where the potential for a chlorine release exists.  Employees 
were involved in determining hazards of the process and subsequent consequences.  The chlorination 
processes were found to be operating safely and no changes were implemented.  The hazard 
assessment was performed on the chlorination processes using the United States Environmental 
Protection Agency RMP*CompTM. Model.  The worst-case release scenario was assumed to be the 
release of a one ton cylinder for a duration of 10 minutes in an enclosed building.  The alternative 
release scenario selected for the Facility w 
as a failure scenario developed during the process hazard 
review and analysis.  In this scenario, the PHA team determined that a leak may develop at a fuse 
plug on a one ton cylinder due to corrosion or a poor bond between the lead alloy and the plug 
retainer would be the most likely cause of a chlorine gas release.  The cylinders are constructed in 
compliance with applicable codes and standards and are hydrostatically tested as required.  
Therefore, the likelihood of this scenario occurring is minimal and an accidental release of this type 
has not occurred at the Facility since it initiated operation.  
 
In addition, the Facility has the capability of responding to and stopping the leak.  For both 
scenarios, the off-site consequence analysis indicated that off-site receptors could be potentially 
impacted by the release of chlorine.  Although off-site areas would be impacted, we believe that 
safety procedures and mitigation measures will reduce the potential for off-site consequences an 

subsequent risks to the surrounding community.  Our safety devices include chlorine leak detectors, 
alarms automatically notify the Sanibel Island Police and Fire Departments, and an automatic system 
shut-off feature triggered by a loss in system vacuum.  In addition, the chlorine cylinders are housed 
in a building with exhaust fans and vents, which would dilute the chlorine gas concentration should 
a release occur. 
 
In order to fulfill the requirements of the Risk Management Program (RMP), we have developed an 
accidental release prevention program and emergency action plan for our facility. The accidental 
release prevention program satisfies the requirements for the EPA RMP and the OSHA PSM 
programs.  The prevention program ensures that our facility is operated under safe conditions and 
that any risk of an accidental release of chlorine is minimized.  The program has been written to 
reduce the potential of an accidental release due to human error, or equipment failure at our facilit 
y.  
In order to prevent the release of chlorine due to human error, our prevention program ensures that 
operating procedures are current and reviewed annually.  Training also plays a vital part in our 
program.  Employees and contractors working on the chlorination processes are required to be 
trained in the chlorination processes and the hazards of chlorine.    
 
To prevent equipment failure that could result in an accidental release, our program ensures that 
equipment inspections, tests, and preventive maintenance are in accordance with accepted 
engineering practices and includes manufacturer's recommendations.  All chlorine cylinders are 
examined upon delivery and are rejected if there are any signs of damage.  In addition, equipment 
pertaining to the chlorine process is visually inspected daily.  The potential for a chlorine release is 
greatly reduced in the chlorination processes due to the use of a vacuum system from the point of 
chlorine withdrawal to its point of mixing with a wa 
ter stream.  In the event that there is a failure in 
chlorination equipment, the system will automatically shutoff (i.e. failsafe).   
 
In the event that a chlorine release occurs and evacuation is necessary, all employees except the 
emergency response team, are required to go to the nearest emergency chlorine shelter identified in 
the evacuation plan and wait for the "all clear" from the emergency response team.  The emergency 
action plan consists of evacuation procedures, facility emergency numbers, and coordination with 
Sanibel Island Fire Department.  The plan also addresses notification procedures to the public and 
the local emergency response agency. 
 
The prevention program ensures that our facility is operated under safe conditions and that any risk 
of an accidental release of chlorine is minimized.  The program has been written to reduce the 
potential of an accidental release due to human error, or equipment failure at our facility.  In order 
to prevent the release of chlorine d 
ue to human error, our prevention program ensures that operating 
procedures are current and reviewed annually.    
 
All existing and proposed future chlorination equipment has been designed according to applicable 
standards and codes.  The Facility maintains records and documentation on equipment inspection 
and tests.  Precautions are taken to ensure that new equipment and processes are inspected and tested, 
that all changes on the process are authorized, and employees are informed of changes. 
 
Active employee participation will ensure the success of the RMP at our facility.  Employees have 
been assigned various tasks to ensure that all elements of the RMP are implemented.  We have 
developed many different forms to assist employees in recording and documenting the various 
elements of the RMP.  
 
The Facility has coordinated the information contained in the RMP with the Local Emergency 
Planning Committee and is willing to conduct tours of our Facility for members of the public.
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