Industrial Chemicals Inc. - Executive Summary

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68.155 Executive Summary 
 
Industrial Chemicals Inc. 
609 Rogers Road 
Dothan, AL 36303-5701 
 
April 1, 1999 
 
Accidental Release Prevention and Emergency Response Policies 
 
The distribution facility is located adjacent to Ross Clark Circle between Denton and Twitchell off Zenith Drive. The business has operated from this location for more than twenty years as a responsible contributor to the community. 
 
The company is a member of the National Association of Chemical Distributors dedicated to the code of management practice of the Responsible Distribution Process. The safe management of chemical products is considered priority to minimize the risk to our community, environment and personnel. 
 
Additionally, Industrial Chemicals Inc. manages the facility in compliance with all Occupational Safety & Health Administration (OSHA), Environmental Protection Agency (EPA), Alabama Department of Environmental Management (ADEM) and the United States Department of Transportation (USDOT) regulations. 
 

o ensure the facility continues to operate in a safe and responsible manner in compliance with all regulations, an extensive risk management system has been developed and integrated into our operating procedures. 
 
Significant components of the system include training, operating procedures for chemical handling, inspection, maintenance, emergency response and incident management. These procedures provided to responsible personnel and management's continual compliance oversight ensures safe chemical management. 
 
The Operations Director, Facilities Manager and Warehouse Manager are designated as having the primary responsibility and accountability to ensure the plan and all components are in compliance and implemented. 
 
Stationary Source Description and Regulated Substances Handled 
 
The facility is used for receipt, storage and distribution of chemical products. There are no manufacturing activities conducted at the site. 
 
Both liquid and dry chemicals are received in small packages and p 
laced in storage for shipment to industrial customers. These prepackaged containers include portable tanks, cylinders and drums. 
 
Chlorine 
 
This gas is packaged in steel cylinders of 2000 and 150 pound size. The product is delivered to the facility on trailers specifically designed to transport the containers. 
 
The chemical is liquefied under pressure and release from the container is in the form of a gas. The cylinders are equipped with safety mechanisms to minimize the possibility of an accidental release and pressure relief devices are installed should the container be exposed to excessive heat from elevated temperature conditions such as that associated with a fire. 
 
Chlorine is shipped off site in small quantities to water treatment facilities using the gas to treat water for the public's use. 
 
The 150 pound containers are stored in secured racks to prevent accidental damage. The 2000 pound cylinders are stored in an area away from equipment traffic and chemicals that may, during  
an incident, contribute to a release from these containers. 
 
During the summer months when Chlorine use is at its peak there may be up to 5 cylinders of 2000 pound capacity and 70 cylinders of 150 pound capacity. 
 
Only authorized and trained personnel are permitted to handle the containers. 
 
Hydrofluoric Acid 70% Solution 
 
This liquid arrives at the facility in 55 gallon drums of 500 and 550 pound capacity. The containers are stored in the warehouse building constructed of concrete floors with concrete curbing around the perimeter to prevent impact to the environment. 
 
The drums are palletized and single stacked in an area with limited access away from traffic. Each container is inspected daily to verify package integrity. 
 
Maximum inventory levels set for this material are 50 drums of either 500 or 550 pound capacity. 
 
Only authorized and trained personnel are permitted to handle the containers. 
 
Sulfur Dioxide 
 
This material is packaged in steel cylinders of 2000 and 150 pound size.  
The product is delivered to the facility on trailers specifically designed to transport the containers. 
 
The chemical is liquefied under pressure and release from the container is in the form of a gas. The cylinders are equipped with safety mechanisms to minimize the possibility of an accidental release and pressure relief devices are installed should the container be exposed to excessive heat from elevated temperature conditions such as that associated with a fire. 
 
Sulfur Dioxide is shipped off site in small quantities to water treatment facilities using the gas to treat water for the public's use. 
 
The 150 pound containers are stored in secured racks to prevent accidental damage. The 2000 pound cylinders are stored in an area away from equipment traffic and chemicals that may, during an incident, contribute to a release from these containers. 
 
During high demand periods inventory levels for this chemical are 2 ton cylinders at 2000 pounds each and 32 cylinders at 150# each. 
 
Only au 
thorized and trained personnel are permitted to handle the containers. 
 
The worst-case scenario(s) and the alternate release scenario(s), including administrative controls and mitigation measures to limit the distances for each reported scenario. 
 
Population estimates are from the Census Bureau and take into account all persons within the toxic distance to endpoint perimeter. It is important to recognize, however, that the regulations require the identification of the potentially impacted population using a circle with a radius that is the maximum distance to the toxic endpoint. In reality, the released material would most likely take the form of a cloud or plume, impacting only a portion of the circle located in the downwind direction from the source. 
 
Chlorine 
 
Worst Case Scenario for Container Storage Process ID 12 
 
A release of the contents from a 2000 pound cylinder in storage as a gas release was used for this worse case scenario because it would be greatest amount of one contain 
er in storage. The EPA's RMP Offsite Consequence Analysis Guidance (OCG Guidance) was used to conduct the modeling. 
 
The release occurred over a 10 minute period at a rate of 200 pounds of liquid released as a gas per minute. The atmosphere was relatively stable with little cloud cover and a wind speed of 3.4 miles per hour during night hours. The physical characteristics of the area are urban with many obstacles. 
 
The estimated toxic distance to endpoint would be 1.3 miles and would involve 3767 persons including residences, schools and the surrounding industrial area. No impact to environmental receptors, such as wildlife refuges, was identified. 
 
Chlorine 
 
Alternate Scenario for Container Storage Process ID 12 
 
This release scenario involved valve failure on a 2000 pound cylinder in storage releasing half of the contents as a gas release. This amount of gas released for the duration was selected because it is expected that the leak can be stopped within this period of time using equ 
ipment designed to repair cylinder leaks. The EPA's RMP Offsite Consequence Analysis Guidance (OCG Guidance) was used to conduct the modeling. 
 
The release occurred over a 30 minute period at a rate of 33 pounds of liquid released as gas per minute. The atmosphere had moderate incoming solar radiation and thinly overcast skies with winds of 6.7 miles per hour during the night hours. The physical characteristics of the area are urban with many obstacles. 
 
The estimated toxic distance to endpoint would be 0.1 mile and involved 49 persons in the surrounding industrial area. 
 
No residences, schools, hospitals or recreation areas were impacted by the release No impact to environmental receptors, such as wildlife refuges, was identified. 
 
Hydrofluoric Acid 70% Solution 
 
Worst Case Scenario for Container Storage Process ID 13 
 
This scenario describes a release of the contents from two drums involving 110 gallons occurring from damage by material handling equipment as a liquid spill. The EPA's 
RMP Offsite Consequence Analysis Guidance (OCG Guidance) was used to conduct the modeling. 
 
The release occurred over a 10 minute period at a release rate of 38.5 pounds (10.6 gallons) of liquid per minute during night hours. The atmosphere was relatively stable with little cloud cover and a wind speed of 3.4 miles per hour. The physical characteristics of the area are urban with many obstacles. 
 
Consideration was given to the storage area within the building with doors that can be closed to reduce the spread of liquid and restrict vapors to a confined space. 
 
The estimated toxic distance to endpoint would be 1.0 mile and involved 1,460 persons in residences and the surrounding industrial area. No impact to environmental receptors, such as wildlife refuges, was identified. 
 
Alternate Scenario for Container Storage Process ID 13 
 
This alternate release scenario involved one 550 pound (52 gallon) container that was damaged by material handling equipment releasing the entire contents. Th 
e EPA's RMP Offsite Consequence Analysis Guidance (OCG Guidance) was used to conduct the modeling. 
 
The total amount released was 550 pounds (52 gallons) occurring over a 10 minute period at a rate of 21.2 pounds per minute. The atmosphere had moderate incoming solar radiation and thinly overcast skies with winds of 6.7 miles per hour during the night hours. The physical characteristics of the area are urban with many obstacles. 
 
Consideration was given to the storage area located within a building. This room has concrete floors with curbing and doors that can be closed to reduce the spread of liquid and restrict vapors to a confined space. 
 
The estimated toxic distance to endpoint was less than 0.2 miles and involved 49 persons in the immediate area of the industrial park. 
 
No schools, hospitals, recreation areas, corrections facilities or environmental receptors, such as wildlife refuges, were impacted by the release. 
 
Sulfur Dioxide 
 
Worst Case Scenario for Container Storage Process 
ID 14 
 
A release of the contents from a 2000 pound cylinder in storage as a gas release was used for this worse case scenario because it would be greatest amount of one container in storage. The EPA's RMP Offsite Consequence Analysis Guidance (OCG Guidance) was used to conduct the modeling. 
 
The release occurred over a 10 minute period at a release rate of 200 pounds of gas per minute. The atmosphere was relatively stable with little cloud cover and a wind speed of 3.4 miles per hour during night hours. The physical characteristics of the area are urban with many obstacles. 
 
The estimated toxic distance to endpoint would be 1.3 miles and would have involved 3767 persons in residences, schools and the surrounding industrial area. No impact to hospital, recreation areas or environmental receptors, such as wildlife refuges, was identified. 
 
Alternate Scenario for Container Storage Process ID 14 
 
This release scenario involved a damaged valve on a 2000 pound cylinder in storage releasing  
half of the contents as a gas release. This amount of gas released for the release duration was selected because it can be expected that leak will be stopped within this period of time using equipment designed to stop leaks on these containers. The EPA's RMP Offsite Consequence Analysis Guidance (OCG Guidance) was used to conduct the modeling. 
 
The release occurred over a 30 minute period at a rate of 33 pounds of liquid released as gas per minute. The atmosphere had moderate incoming solar radiation and thinly overcast skies with winds of 6.7 miles per hour during the night hours. The physical characteristics of the area are urban with many obstacles. 
 
The estimated toxic distance to endpoint would be 0.1 mile and involved 49 persons in the surrounding industrial area. 
 
No residences, schools, hospitals, recreation areas and the surrounding industrial area were impacted by the release. No impact to environmental receptors, such as wildlife refuges, was identified. 
 
General Accidental  
Release Prevention Program and Chemical-Specific Prevention Steps 
 
The facility has an aggressive accidental release prevention program that is based upon employee training, chemical safety awareness, equipment and facility management. 
 
Training includes both the classroom environment and observation by management to verify competency. Classes are designed to achieve maximum results within the time period and knowledge is determined by verbal and written test. Management follows a yearly schedule issuing course work on a weekly basis to the facility manager. Classes are held at the facility on a weekly basis for one to two hours. Attendance is mandatory for all employees including drivers and warehouse personnel and is verified by the Operations Director. 
 
New employees are required to receive an extensive orientation to the operating procedures for each phase of the operation including material handling equipment, transportation vehicle loading and unloading, transportation equipment  
operations, liquid material transfers, personal protection, hazard recognition and safe work practices. 
 
Employees not having worked in a process receive an introduction by thorough procedural documentation review and pairing the employee with a person familiar with the process for an unspecified period. Management within the guidelines of the program verifies competency of safe operating practices. 
 
The company provides training according to the following regulatory and association requirements: 
 
Occupational Safety and Health Administration 
 
Hazardous Waste Operations 
Worker Right-To-Know laws 
Powered Industrial Trucks 
Material Handling and Storage 
Hazardous Materials 
Toxic and Hazardous Substances 
Personal Protection Equipment 
 
Environmental Protection Agency 
 
Chemical Accident Prevention 
Solid Waste Management Guidelines 
Standards for Hazardous Waste Generators 
Superfund, Emergency Planning and Community Right-To-Know Program 
 
United State Department of Transportation 
 
Federal High 
way Administration Federal Motor Carrier Safety Regulations 
 
Research and Special Programs Administration 
 
Transportation Regulations for Hazardous Materials 
Employee Training Requirements for Hazardous Materials 
 
Alabama Department of Environmental Management Hazardous and Non-hazardous Waste Management Programs 
 
National Association of Chemical Distributors Responsible Distribution Process 
 
Facility Management 
Employee Training 
Product Stewardship 
Waste Management 
Community Outreach 
Carrier Selection 
 
Maintenance Systems 
 
The program includes an aggressive maintenance and process inspection system to verify all systems are in proper working order and repairs are accomplished promptly to minimize the risk of release from equipment failure. 
 
Transportation equipment used to move product on the public roads and highways are inspected both before and after each trip by qualified and competent operators. The vehicles are maintained according to a strict schedule by a company with a strong 
reputation in transportation equipment maintenance. 
 
All portable tanks, know as tote tanks, are designed for and dedicated to specific products. Each container is inspected before filling using a systematic approach to verify that each and every component is in suitable condition. 
 
Material handling equipment such as fork lifts are inspected daily and each unit receives periodic maintenance according to a schedule. All equipment used in the handling of material are routinely inspected for defects and promptly removed from service when found defective. 
 
The loading and unloading area for transport vehicles is within the building on a concrete surface. A release occurring during the loading or unloading of packages can be contained to this area. 
 
Materials stored within buildings are located in areas specific to their hazard class to prevent one group of hazard class from impacting another during an incident. 
 
All buildings are constructed of poured concrete floors to minimize the poss 
ibility of a release contacting the ground and impacting the environment. Equipment used in the areas to move containers is designed for their intended use. 
 
Storage areas are routinely inspected according to a schedule to minimize risks associated with improper material storage. 
 
Buildings are equipped with 24 hour monitoring systems to alert authorities of high heat smoke and fire conditions. Emergency responders are dispatched to the scene by a monitoring service. Intrusion is monitored after hours to prevent unauthorized access to the property. The grounds are secured to prevent unauthorized access to the facility 
 
Five-year Accident History 
 
There have been no accidents or incidents associated with the regulated chemicals during the past five years prior to the date of the plan. 
 
Emergency Response Program 
 
The emergency response program document and procedures were developed when the Environmental Protection Agency enacted the Superfund Amendment and Reauthorization Act known as  
the Emergency Planning and Community Right-To-Know Program or SARA Title III. 
 
This program requires facilities having certain regulated substances in amounts exceeding threshold quantities to notify the State Emergency Response Commission (ERC), Local Emergency Planning Committees (LEPC) and fire departments that would respond to the facility in an emergency of the existence of these substances. 
 
This information is updated annually and made available to the public through the LEPC. Documentation includes the chemical inventory of regulated substances, the container types and storage conditions, maximum amounts at the site during the year, average daily amounts and the number of days on site. 
 
In addition, site descriptions, drawings of the facility, locations within the facility of each chemical, surface area, equipment locations as well as emergency equipment are included in the documents. 
 
The emergency response and contingency plan developed and coordinated with local responders i 
ncludes a description of emergency response equipment on site, contacts names and phone numbers, procedures for public notice, guidelines for notifying emergency response agencies and personnel, information gathering forms and methods and reports that must be completed and filed with regulatory agencies. 
 
The employee emergency response training program is included with this document and is used by the facility to train personnel in response techniques. The program provides training for hazardous incident recognition, personnel protection equipment selection and use, characteristics of hazardous chemicals and the methods for response, cleanup and decontamination. 
 
Planned Changes to Improve Safety 
 
Plans are continually updated to improve management of chemicals and reduce the risks associated with handling chemical products. 
 
Plan updates are the result of coordination with local responders, inspections by regulatory agencies, training sessions, process changes and new risk management 
programs and regulations enacted by the government. 
 
Presently all areas are being studied to identify technically, procedurally and economically feasible passive and active risk management strategies to further enhance the safe operation of the facility.
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