Tosco Refining Company - Alliance Refinery - Executive Summary

| Accident History | Chemicals | Emergency Response | Registration | Source | Executive Summary |

Tosco Refining Company Alliance Refinery 
Risk Management Plan 
Executive Summary 
 
The Tosco Refining Company Alliance Refinery is located south of  Belle Chasse, Louisiana.  Alliance is a petroleum refinery which processes raw crude oil into many important products including propane, diesel fuel, gasolines, jet fuel, and other intermediate refinery products.   
 
As a company, our goals include providing a safe workplace, protecting the health and welfare of our community, producing safe products and minimizing environmental impacts. 
 
To achieve these goals, Tosco Refining Company Alliance Refinery employs approximately 600 top-notch employees and contractors to run and maintain the refinery in optimum condition.  Alliance Refinery started operations in 1971 and remains one of the country's most efficient and modern refineries.   
 
In 1996, the EPA implemented a new regulation  called the Risk Management Program, or RMP, for facilities that handle certain toxic and flammable chemicals.  As 
part of this new policy, facilities must provide information to the EPA about these chemicals, the potential risk they pose to the community, and the many ways companies like Tosco manage those risks.   
 
Alliance Refinery processes crude oil, which inherently requires the use and production of flammable chemicals in quantities large enough to be regulated by RMP.  In addition, the refinery uses two toxic chemicals in large enough quantities to be regulated by RMP.  These two chemicals are hydrogen fluoride (HF), which is used in the alkylation process, and chlorine (Cl2), which is used for water treatment. 
 
Below is a discussion of Tosco Refining Company Alliance Refinery's Risk Management Program followed by a discussion of the many systems that we have in place to prevent incidents from occurring.  The RMP includes: 
1.0  Hazard Assessment 
2.0  Accidental Release Prevention Program 
3.0  Emergency Response Program 
 
Sections 4.0 and 5.0 discuss Tosco's accident release prevention and r 
esponse policies, and future safety and environmental improvements, respectively. 
 
1.0  Hazard Assessment 
One of the most significant requirements of the RMP rule is the requirement of a hazard assessment.  This assessment provides the refinery and the public information on the types and extent of the hazards at the facility.  The hazard assessment consists of two exercises:  an offsite consequence analysis and a five-year accident history. 
 
1.1 Offsite Consequence Analysis 
For the off-site consequence analysis, companies must report worse case scenarios (WCS) for each class of regulated substances  -- flammable and toxic.  Alternative release scenarios are required for flammable chemicals as a class and for each RMP toxic chemical above the threshold quantity at the facility. 
 
Worst Case Scenarios (WCS) 
A worst case scenario (WCS) is defined as the rapid and complete release of a RMP chemical that results in the greatest potential impact distance under conditions that maximize the pot 
ential impact distance (temperature, windspeed).  It is also assumed that none of the site's safety systems are operational. 
 
Flammables 
Tosco Refining Company Alliance Refinery's WCS for flammables is based on the failure of a butane storage sphere, which contains a maximum of 8.5 million pounds of butane, under the worst possible weather conditions, with no safety controls considered. The scenario assumes that the release results in a vapor cloud explosion.  It is extremely unlikely that a release would occur, that all safety features would fail, and that the worst case weather conditions would prevail all at once.  Tosco Refining Company Alliance Refinery has systems in place to prevent and respond to incidents in the butane storage sphere area, such as pressure relief devices, level indicators and routine inspections. 
 
Toxics 
Tosco Refining Company Alliance Refinery's worst case scenario for toxics is based on the failure of the hydrogen fluoride (HF) acid settler, which holds up t 
o 560,000 pounds of HF.  Using EPA's guidelines, the failure would result in a release of 560,000 pounds of HF in ten minutes.  Again, no safety controls are considered in this scenario which includes the worst case weather conditions.  The chance of this type of event occurring is extremely remote.  Tosco Refining Company Alliance Refinery has many systems in the HF area to prevent and respond to incidents including HF detectors, a containment dike, and a water spray system that can be used in the event of a release. 
 
Alternative Release Scenarios 
EPA requires companies to also report alternative release scenarios that are based on more realistic data.  The alternative release scenarios represent potential incidents that could occur at the refinery, and they include the many controls that we have in place - we can count on our important safety systems that help us prevent incidents and respond to emergencies. 
 
The EPA guidelines require us to provide alternative case scenarios for all 
RMP chemicals that exceed their threshold quantities.  The flammable RMP chemical at Tosco Refining Company Alliance Refinery is butane and the toxic RMP chemicals are hydrogen fluoride (HF) and chlorine (Cl2).    
 
Flammables 
Tosco Refining Company Alliance Refinery's alternative release scenario for flammables is based on the failure of an eight inch pipe on a butane sphere, in which 612,000 pounds of butane is released in less than ten minutes, under the typical weather conditions. The butane would be released in both liquid and vapor form; the scenario assumes that the liquid butane released forms a pool which ignites and burns. As mentioned previously, Tosco Refining Company Alliance Refinery has systems in place to prevent and respond to incidents in the butane storage sphere area, such as pressure relief devices, level indicators and routine inspections. 
 
Toxics 
Tosco Refining Company Alliance Refinery's alternative release scenario for HF is based on the failure of a truck unlo 
ading hose, in which 713 pounds of HF would be released in less than ten minutes under typical weather conditions.  Water spray mitigation has been considered. Tosco Refining Company Alliance Refinery has many systems in the HF area to prevent and respond to incidents including HF detectors, a containment dike, and a water spray system that can be used in the event of a release. 
 
Tosco Refining Company Alliance Refinery's alternative release scenario for Cl2 is based on the failure of a 3/4 inch line, in which 560 pounds of Cl2 would be released in less than ten minutes under typical weather conditions.  Tosco Refining Company Alliance Refinery inspects cylinders before placing them on-line.  In the case of an incident Cl2 patch kits are on-site and would be used. 
 
1.2  Five Year Accident History 
The Tosco Refining Company Alliance Refinery has not had a release of an RMP toxic or flammable compound that meets the requirement of the RMP rule in the last five years.  However, we believe 
it is important to learn from all incidents; therefore, we have an incident investigation program in place to review incidents that occur at the refinery and to prevent them from happening in the future. 
 
The information above regarding Tosco Refining Company Alliance Refinery RMP WCSs may cause concern but it is important to take into consideration that the EPA WCS guidance is overly conservative; therefore, it is highly unlikely that a WCS event would occur.  The following sections describe Tosco's commitment to people and the environment and the many programs that we have in place to prevent major incidents from occurring at our refinery. 
 
 
2.0  Accidental Release Prevention Program Steps 
It is believed that if a refinery has a successful  process safety management system in place, most incidents can be avoided.  The Occupational Safety Health Administration (OSHA) has promulgated a regulation which provides guidance to industry for developing and maintaining a process safety mana 
gement program (PSM).  Tosco Refining Company Alliance Refinery initiated its PSM program in the early 90's.  The RMP general accident prevention program is based on the OSHA PSM standard; therefore we have provided a summary of the refinery's  PSM elements below. 
 
* Employee Participation - All employees are encouraged to actively participate in the prevention                   programs at Alliance. 
* Process Safety Information - At Alliance, we keep detailed information about our processes, chemicals, and equipment.  This allows us to operate and maintain the refinery safely. 
* Process Hazard Analysis (PHA) - PHA's are studies that teams at the refinery perform to make sure that the equipment is designed, built, and operated within safe limits. 
* Operating Procedures - Alliance has written procedures that address different modes of operation at the refinery.  These procedures serve as a reference for experienced personnel and a training tool for new employees.  The procedures are cer 
tified annually. 
* Training - The refinery has an extensive training program that addresses both training for new employees and refresher training for all operators.  Employees are not allowed to work independently until they have demonstrated adequate knowledge in a process, and records are kept on each employee's progress. 
* Contractors - Contract workers at the refinery are expected to follow the same safety procedures as Tosco employees.  Alliance evaluates contractor safety performance when selecting a contractor and monitors contractors to ensure that they are working safely. 
* Pre-Startup Safety Reviews (PSSRs) - Alliance performs PSSR's when there is an addition or change at the refinery.  This ensures that the change is compatible with the unit design.  This provides a safety check prior to startup of equipment. 
* Mechanical Integrity - The mechanical integrity program at Alliance ensures that existing equipment is in working order and that new equipment is suitable for its in 
tended use. 
* Safe Work Practices - Alliance has many safe work practices in place to ensure safety.  These include plant security, hot work and confined space procedures, and procedures to secure equipment before maintenance is performed. 
* Management of Change (MOC) - The MOC system at Alliance ensures that any changes to equipment are consistent with existing equipment and procedures. 
* Incident Investigation - Alliance investigates all incidents and near misses at the refinery.  This provides a mechanism to learn from our accidents and improve safety. 
* Compliance Audits - Every three years, Alliance conducts an audit to make sure that all of the safety programs are in place and functioning properly. 
 
In addition to the General Accidental Release Prevention Program elements, Alliance has safety features on it's process units to help (1) contain/control a release, (2) quickly detect a release, and (3) reduce the consequences of, or mitigate a release.  The following types of safety  
features are used in various processes: 
 
(     Release Detection 
       Hydrocarbon detectors with alarms 
       Toxic gas detectors with alarms 
 
(     Release Containment/Control 
       Process relief valves that discharge to a flare system to capture and incinerate episodic releases 
       Scrubbers to neutralize chemical releases 
       Valves to permit isolation of the process (manual or automated) 
       Automated shutdown systems for specific process parameters (e.g., high level, high temperature) 
       Vessel to permit partial removal of the process inventory in the event of a release (e.g., dump  
          tank) 
       Curbing or diking to contain liquid releases 
       Redundant equipment and instrumentation (e.g., uninterruptible power supply for process control    
         system, backup firewater pump) 
       Atmospheric relief devices 
 
(     Release Mitigation 
       Fire suppression and extinguishing systems 
       Deluge systems for specific equipment 
 
   Trained emergency response personnel 
       Personal protective equipment (e.g., protective clothing, self-contained breathing apparatus) 
 
 
3.0  Emergency Response Program 
 
The Tosco Refining Company Alliance Refinery has its own emergency response team that covers Fire Response, Hazmat Response, and First Aid Response on a 24 hour basis.  The emergency response team trains regularly to maintain their readiness and preparedness to tackle any incident involving flammable or toxic chemicals handled by the refinery, and other occupational incidents.  
 
The Tosco Refining Company Alliance Refinery maintains a written emergency response program, which is in place to protect worker and public safety as well as the environment.  The program consists of procedures for responding to a release of a regulated substance, including the possibility of a fire or explosion if a flammable substance is accidentally released.  The procedures address all aspects of emergency response, including 1) pro 
per first-aid and medical treatment for exposures, 2) evacuation plans and accounting for personnel after an evacuation, 3) notification of local emergency response and the public if a release occurs, and 4) post-incident cleanup and decontamination requirements.  
 
In addition, the Tosco Refining Company Alliance Refinery has procedures that address maintenance, inspection and testing of emergency response equipment, as well as instructions that address the use of emergency response equipment.  Employees receive training in these procedures as necessary to perform their specific emergency response duties.   
 
The emergency response program is updated when necessary based on modifications made to refinery processes or other refinery facilities.  The emergency response program changes are administered through the Management of Change process, which includes informing and/or training affected personnel in the changes. 
 
The overall emergency response program for the Tosco Refining Company  
Alliance Refinery is coordinated with the Belle Chasse Fire Department and Plaquemines Parish Local Emergency Planning Committee (LEPC).  This coordination includes close liaison with refinery emergency response teams and periodic meetings between local emergency response officials, local government officials, and industry representatives.  The Tosco Refining Company Alliance Refinery has 24 hour communications capability with appropriate officials and emergency response agencies.  This provides a means of notifying the public of an incident, if necessary, as well as facilitating quick response to an incident.  Tosco Refining Company Alliance Refinery conducts periodic emergency drills that involve the LEPC, emergency response agencies, and the refinery provides annual refresher training to local emergency responders regarding the hazards of regulated substances in the refinery. 
 
 
4.0  Accidental Release Prevention and Response Policies 
 
Alliance Refinery maintains the high level of co 
mmitment to Safety, Health and the Environment.  Everybody who works for Tosco, is responsible for good Safety, Health and Environment performance.  As a company, we will continue to minimize the environmental and health impacts of our operation by reducing waste, emission and discharges, and using energy efficiently.  We produce quality products that can be used safely by our customers. 
 
Safety Performance 
Tosco's commitment to safety of people and the environment has been shown through the  many awards we have received and the milestones that we have achieved.  Alliance Refinery has received numerous awards from national organizations such as the American Petroleum Institute (API) and the National Petroleum Refiners Association (NPRA), most recently winning the NPRA's Gold Award for a 47% improvement in OSHA Recordables over a three year period.  The Alliance Refinery employees received the Award of Honor from the New Orleans Metropolitan Safety Council in May, 1999, for creating one 
of safest, local work environments in a 9 parish area. 
 
Environmental Performance 
 
As part of Tosco's environmental policy, we are committed to the protection and respect of the environment within which the refinery operates.  We operate in such a manner as to minimize the refinery's impact on the environment while competitively producing quality petroleum products.  Evidence of our commitment is in the many environmental programs we have in place at the refinery and the initiatives that we have taken to make the Alliance Refinery an efficiently run and environmentally friendly refinery.   
 
Environmental emissions from the refinery have been declining significantly throughout the last decade due to Alliance's strong commitment to the environment and with improved technology that is now available.  Since 1992, the Alliance Refinery has reduced emissions 95%.  It is Tosco's goal to identify all areas within the refinery where appropriate feasible technology can be applied to minimize en 
vironmental releases even further in the future.  Evidence of this is that for the third consecutive year, the Alliance Refinery has earned a special citation from the Governor's Environmental Leadership Awards program for its work to prevent pollution.  This commitment is further demonstrated by the investment of approximately 200 million dollars since 1988 to complete a series of environmental projects to not only comply with new environmental regulations but also to improve environmental performance.   
 
In addition,  in December of 1998, Alliance Refinery received a coveted international certification, marking the first time a U.S. oil refinery has ever earned the "ISO-14001" title.  ISO-14001 is a set of vigorous environmental standards developed by the International Standards Organization (ISO), an organization created for those countries that have little governmental involvement in the industry.  The ISO-14001 standard provides a guide for companies in measuring the thoroughness  
and effectiveness of their environmental management system. 
 
 
5.0  Future Safety and Environmental Improvements  
 
Everybody who works for Tosco is responsible for good safety and environmental performance.  Good performance in these areas is critical to the success of our business and is strongly promoted by the company's top executives. 
 
Our goals include providing a safe workplace, protecting the health and welfare of our community, producing safe products and minimizing environmental impacts. 
 
We will continue to minimize the environmental and health impacts of our operations by reducing waste, emissions and discharges, and using energy efficiently.  We produce quality products that can be used safely by our customers. 
 
Our business plans include measurable Safety, Health and Environmental targets.  We are all committed to meeting them.
Click to return to beginning