Cedar Lake Plant - Executive Summary

| Accident History | Chemicals | Emergency Response | Registration | Source | Executive Summary |

Source and Process Description 
 
Cooper Natural Resources and its predecessor companies have produced the industrial mineral, 
sodium sulfate, from underground brine deposits in west Texas since 1933. Their Cedar Lake 
Plant, located in northeastern Gaines County, has been in operation since 1965. The sodium 
sulfate produced by the plant is a high purity, non hazardous salt that is shipped to customers 
throughout the United States for use in the detergent, glass, paper, dyestuffs and animal 
husbandry industries. 
 
The plant is supplied by shallow wells located in the adjacent, highly saline, Cedar Lake. The 
produced brine is over nine times the salinity of seawater. This brine is conveyed to the plant by 
pipelines. Refrigeration units in the plant are then used to cool the brine and cause the 
precipitation of the hydrous form of sodium sulfate, Glauber's salt, Na2SO4 X 10 H2O. The 
refrigeration system contains approximately 67,000 lbs. of ammonia. The hydrous salt produced 
by refrigeration 
is then recovered by filtration and sent to the drying plant where a vapor 
recompression unit melts the salt in its waters of hydration. Concentration of the saturated 
solution results in precipitation of anhydrous sodium sulfate, the marketable product. The 
anhydrous sodium sulfate is subsequently recovered by centrifuges and dried prior to shipment. 
 
No reagents or reactive chemistries are used in the process. The method of operation is based on 
simple phase chemistry alone. The plant produces only high purity sodium sulfate salt and 
ultra-pure steam condensate. 
 
Program Status As more fully described herein, the plant meets the eligibility requirements of 
Program 1 status as provided in 68.12(b) of the RMP Rule because it meets all of the following 
requirements: 
 
(l)For the five years prior to the submission of an RMP, the process has not had an accidental 
release of a regulated substance where exposure to the substance, its reaction products, 
overpressure generated by an explosion 
involving the substance, or radiant heat generated by a 
fire involving the substance led to any of the following offsite: (I) death; (ii) injury; or (iii) 
response or restoration activities for an exposure of an environmental receptor; 
 
(2)The distance to a toxic or flammable endpoint for a worst-case release assessment conducted 
under Subpart B and 68.25 of this part is less than the distance to any public receptor, as defined 
in 68.30 of this part; and 
 
(3)Emergency response procedures have been coordinated between the stationary source and 
local emergency planning and response organizations. 
 
Hazard Assessment: Release Scenarios 
 
A Hazard Assessment has been conducted on the facility under the guidelines of Model Risk 
Management Program and Plan for Ammonia Refrigeration. The results of the Offsite 
Consequence Analysis for both a worst-case and an alternative accidental release scenario may 
be found in the enclosed Data Elements Checklist. 
 
Worst-Case Release Scenario: For the wors 
t-case evaluation the amount of ammonia 
hypothetically released was taken as the largest mass of ammonia that is liquefied under pressure 
in any vessel in the ammonia refrigeration system. This would be the ammonia accumulator 
which is an outside vessel containing 6,060 lbs. of liquid ammonia. A duration of ten minutes 
was used in the evaluation resulting in a predicted distance to the toxic endpoint of 1.4 miles. 
The direction of the plume, and thus the potentially impacted area, would of course be dependent 
upon the wind direction during the release incident. As shown on the accompanying map, See 
Attachment 1, this area is unimproved ranch land. There is one unoccupied house and Farm to 
Market Road 1066 on the northern extremity of the subject area. Thus, there would be no danger 
to the public of a release of this magnitude. There could be a potential danger to emergency 
response units approaching down the company's private road from the north. As stated in the 
Certification section  
of this report, the public emergency responders should not enter this area 
except as arranged with the emergency contact indicated herein. 
 
Alternative Release Scenario: For the purpose of this analysis, the alternative release scenario 
would be more likely to occur than the worst-case scenario. The circumstances of the alternative 
scenario were a release through a l/4" effective diameter orifice leading to an airborne release. 
The rate of release from a high-pressure receiver would be 100 lb/min. The predicted distance to 
the Toxic Endpoint is 1,020 ft., which would pose no danger to the public. 
 
Accidental Release Prevention Program and Chemical-Specific Prevention Steps 
 
Because anhydrous ammonia is a regulated substance, the plant is also covered by the U.S. 
Occupational Safety and Health Administration's (OSHA) process safety management standard 
(PSM). Additionally, the plant submits an annual "Tier II" report to the State Emergency 
Response Commission, the Local Emergency Plannin 
g Committee (LEPC) for Gaines County as 
well as the three local fire departments. The TIER II report lists all hazardous chemicals, 
including anhydrous ammonia, that may be held above the threshold quantity at the plant. The 
report also describes the chemical properties and location of each chemical in the plant in order 
to assist emergency responders should they ever be called to the facility. 
RMP - Executive Summary Page 3, Continued 
 
Cooper Natural Resources is an active participant in the Responsible Care program of the 
Chemical Manufacturers Association (CMA). The CMA represents nearly 200 chemical 
manufacturers who account for 90 percent of the country's basic chemical production. The 
CMA's Responsible Care initiative is a widely recognized program of continuous improvement 
in six Codes of Management Practice covering health, safety and the environment. 
 
Releases at our facility are prevented by well-maintained equipment and well-trained personnel. 
The company has not hesitated t 
o invest the resources to both maintain and upgrade the ammonia 
system: $158 000 in capital having been spent for this purpose in the past 18 months. Plant 
personnel receive annual ammonia training. The plant's process safety management program, an 
OSHA regulation, pertains to ammonia directly and has been an important safeguard in the safe 
operation and emergency preparedness of the plant. 
 
The plant is required to report any ammonia spills exceeding 100 lbs., the Reportable Quantity 
(RQ) for ammonia. These reports are made to the Federal, State and County regulatory agencies. 
Notwithstanding the safety consequences of an ammonia release. it may be noted that anhydrous 
ammonia is a commonly used agricultural fertilizer in the surrounding region where amounts 
much greater than the RQ are routinely applied directly to the soil. 
 
Five Year Accident History 
 
There have been no accidental releases with offsite consequences, as defined in 68.10(b)(1), see 
eligibility status above, at the fa 
cility within the past five years. 
 
Emergency Response Program 
 
The Cedar Lake Plant is prepared to respond to an emergency situation with ammonia. The 
facility has a Safety Director on staff. Its emergency response team consists of plant personnel 
who are knowledgeable of the plant process. They are trained in emergency response and conduct 
drills on a quarterly basis. They have the emergency gear necessary to enter an ammonia 
environment for rescue. 
 
In the event of a release, the response team is equipped to enter a dangerous area to close 
shutoff valves or take other measures to isolate the leak, thereby mitigating the release. They are 
also available and trained to assist the emergency responders in containing the release as quickly 
as possible. 
 
A disaster drill is held annually in cooperation with the Gaines County Sheriff's Dept., the local 
fire departments and EMS units. This drill has proven to be very beneficial in coordinating the 
plant's response procedures with the local  
emergency planning and 
response organizations. 
 
Furthermore, a copy of this Risk Management Plan will be supplied to the local emergency 
responders and Gaines County LEPC. 
 
Planned Changes to Improve Safety 
 
The potential risks of ammonia usage are taken very seriously at our plant. The safety of both our 
employees and neighbors has been, and will continue to be, our number one priority at Cooper 
Natural Resources. Training and retraining of all of our employees is an on-going activity of our
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