Chicago Specialties 115th Street - Executive Summary

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Executive Summary 
 
Facility Information  
 
The Chicago Specialties plant has approximately 130 employees.  The facility produces  
organic dyes and pigments and intermediate cyclic organics.  Chicago Specialties uses  
three regulated chemicals in processes above threshold quantities.  The facility uses  
sulfur trioxide as a feed material in the manufacture of paracresol, and sulfur dioxide as a  
diluent in the paracresol process.  The facility stores up to 215,000 pounds of sulfur  
trioxide in an indoor storage vessel, and up to 50,000 pounds of sulfur dioxide in an  
outdoor storage vessel.  The facility also uses anhydrous ammonia as a feed material in  
the production of isopthalonitrile.  The regulated anhydrous ammonia process is a storage  
vessel, which can store up to 175,000 pounds of the material.   
 
Risk Management Planning 
 
In addition to our existing information sharing practices, Community Right-to-Know,  
emissions inventories, and Title V Permit, Chicago Specialties shares in 
formation  
regarding the chemicals used and their associated risk with the public.  The facility uses  
both passive and active mitigation to minimize the likelihood of releases and their impact  
to the public and to the environment.  These mitigation systems emergency shutdown  
equipment and revised operating procedures and equipment for the covered sulfur  
dioxide process.  The sulfur trioxide process uses dikes, sumps, emergency shutdown  
equipment, and a CO2 cryogenic mitigation system, which entails freezing the material if  
released. 
 
Accident History and Safety Improvements 
 
The table below lists Chicago Specialties' five-year accident history of all accidental  
releases from covered processes, which resulted in off-site evacuations, shelter-in-place,  
property or environmental damage, injuries, or significant property damage on-site.  The  
incident in 1997 occurred on August 4.  During the incident a transfer hose failure  
released 8,500 pounds of sulfur trioxide in to the envir 
onment, of which 7,000 pounds  
were released to the atmosphere.  A portion of the local vicinity was evacuated.  There  
were no deaths or off-site property damage associated with this accident.  
 
The facility conducted an extensive safety review after the incident.  Chicago Specialties  
has determined that the most likely cause of the accident was water the unloading  
connections of the tanker truck, which was loading sulfur trioxide into the facility's  
storage tank.  The facility has subsequently installed several safety measures to reduce  
the likelihood of a reoccurrence of this type of incident: improved and upgraded  
equipment involved in the process, revised training, maintenance, emergency response  
plans, and operating procedures.  The facility also installed new mitigation systems,  
which significantly reduced the risk of such an occurrence happening again.   
Chicago Specialties' 5-year Accident History 
 
The five year accident history was prepared in accordance with 68.42.  T 
he accidents  
reported in the RMP data elements only include accidents related to a regulated chemical  
(SO2, SO3 or Anhydrous Ammonia) that resulted in deaths, injuries, or significant  
property damage on-site or known offsite deaths, injuries, evacuations, sheltering in  
place, property damage, or environmental damage.  There were four releases of regulated  
chemicals in the past five years.  Only the August 04, 1997 release meets the  
requirements of 68.42 for a release which must be reported. 
 
Year    1994    1995    1996    1997    1998 
Number    0    0    0    1    0 
 
Prevention Program 
 
Chicago Specialties believes the best way to manage risk is to prevent accidents.   
Chicago Specialties has performed a HAZOP analysis to identify and reduce the risk  
posed by the RMP covered processes.  The prevention program will continue to reduce  
the risk through improved safety.  Chicago Specialties' process safety management  
program includes but is not limited to; process safety information, operating procedures,  
tr 
aining, pre-startup safety review, mechanical integrity, and management of change.  In  
addition, the facility has incorporated process controls including, relief and check valves,  
manual and automatic shutoffs, interlocks, alarms, backup pumps, grounding equipment,  
rupture disks, sprinkler systems, fire walls and blast walls where appropriate. 
 
Emergency Response Policy 
 
Chicago Specialties has coordinated with the Local Emergency Preparedness Committee  
(LEPC) and Fire Chief Frank Moriarty.  Chicago Specialties has prepared an extensive  
written emergency response plan.  Specifically, the emergency response plan works to  
minimize the amount of material released to the environment and to establish control and  
mitigation of any releases in an expedited manner while communicating the nature of the  
incident to the public and local agencies. 
 
Worst-Case Release Scenario and Alternative Release Scenarios 
 
The RMP rule requires development of scenarios or examples for an accidental rel 
ease of each RMP regulated chemical.  The scenarios developed for Chicago  
Specialties are outlined in the table below.   
 
Chemical 
About the Chemical 
Release Type 
Accident Prevention In- 
Place 
Scenario Description 
Emergency Response  
Measures 
Sulfur  
Trioxide 
Colorless liquid, forms  
crystals at 90oF 
Worst-case  
Release 
?    Standard Operating  
Procedures 
?    Tank Inspections 
 
 
?    Instantaneous failure of tank walls 
?    Worst possible weather conditions  
(low wind, low humidity) 
?    Total release of entire contents of  
tank (215,000 lbs) inside the  
building 
?    Communication with  
public agencies; 
?    Coordinate with LEPC; 
?    Emergency Response  
Plan; 
?    Personal Protective  
Equipment; 
?    Response Equipment. 
Sulfur  
Dioxide 
Sulfur Dioxide is a  
colorless gas or liquid,  
with a strong pungent  
odor. 
Alternative  
Case Release 
?    Relief Valves 
?    Rupture Disk 
?    Manual Shutoffs 
?    Automatic Shutoffs 
?    Interlocks 
?    Rupture disk over-pressurization  
?    Average weather conditions 
? Duration of vent release - 4  
minutes 
See above 
Sulfur  
Trioxide 
Colorless liquid, forms  
crystals at 90oF 
Alternative  
Case Release 
?    Relief Valves 
?    Rupture Disk 
?    Manual Shutoffs 
?    Automatic Shutoffs 
?    Interlocks 
?    Transfer hose rupture 
?    Average weather conditions 
?    Release of 8,500 lbs. 
 
See above 
Anhydrous  
Ammonia 
Colorless caustic gas  
with pungent odor 
Alternative  
Case Release 
?    Relief Valves 
?    Rupture Disk 
?    Manual Shutoffs 
?    Automatic Shutoffs 
?    Interlocks 
?    2,100 lb/min release per  
EPA RMP Ammonia Guidance  
Document 
See above
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