MarkWest Hydrocarbon, Inc. - Siloam Facility - Executive Summary

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Risk Management Plan 
Executive Summary 
 
MarkWest Hydrocarbon, Inc. - Siloam Facility 
 
1.    Accidental Release Prevention and Emergency Response Policies 
 
The MarkWest Hydrocarbon, Inc. (MarkWest) - Siloam facility located in South Shore, Kentucky is strongly committed to employee, public, and environmental safety.  This commitment is inherent to a comprehensive accidental release prevention program that covers such areas as design, installation, operating procedures, maintenance, and employee training associated with the processes at our facility.  It is the policy of MarkWest to implement appropriate controls to prevent the possible release of regulated substances.  Unforeseeably, if such a release does occur, MarkWest is completely coordinated with the Greenup County, Kentucky and Scioto County, Ohio Local Emergency Planning Committees (LEPCs) which provide emergency response personnel to control and mitigate the effects of the release. 
 
2.    The Stationary Source and the Regulated Subst 
ance Handled 
 
The primary function of the MarkWest facility encompasses processing, storage, and wholesale distribution of various liquified petroleum gases (LPGs).  The following LPGs are present at the facility: propane, normal butane, isobutane, natural gasoline (pentanes and hexanes), and mixed feed natural gas liquids (a combination of all the previously mentioned LPGs commonly referred to as Y-grade).  All of these substances are regulated due to their flammable and explosive nature.   
 
The facility receives the mixed feed Y-grade from pipeline, tank truck, and rail car.  The Y-grade is stored in above ground vessels and then processed at the facility into propane, normal butane, isobutane, and natural gasoline.  These products are stored in both above ground vessels and also, in the case of propane and normal butane, in underground caverns. 
 
These products are then distributed from the facility by tank truck, rail car, and, in the case of normal butane, isobutane, and natural ga 
soline, by barge. 
 
The facility contains a total of 30 above ground vessels and 2 underground storage caverns.  Table 1 summarizes the storage capacities of each of the vessels and caverns and also the type of product stored in each.  Table 2 summarizes the vessels and storage capacities for propane, normal butane, isobutane, natural gasoline, and Y-grade, respectively.  
 
 
TABLE 1 
TOTAL STORAGE CAPACITIES 
MarkWest Hydrocarbon, Inc. 
Siloam Facility 
South Shore, Kentucky 
 
 
 
Product Stored 
Tank ID 
Capacity 
(gallons) 
Propane 
Normal Butane 
Isobutane 
Natural Gasoline 
Natural Gas Liquids 
SV-100 
60,000 
 
 
 
 

SV-101 
18,000 
 
 
 
 

SV-102 
18,000 
 
 
 
 

SV-103 
30,000 
 
 
 
 

SV-104 
30,000 
 
 
 
 

SV-200 
57,707 

 
 
 

SV-201 
57,744 

 
 
 
 
SV-202 
57,671 

 
 
 
 
SV-203 
57,754 

 
 
 
 
SV-204 
59,582 

 
 
 
 
SV-205 
59,672 

 
 
 
 
SV-300 
32,133 
 

 
 
 
SV-301 
32,221 
 

 
 
 
SV-400 
15,155 
 
 

 
 
SV-401 
26,950 
 
 

 
 
SV-402 
30,000 
 
 

 
 
SV-403 
42,151 
 
 

 
 
SV-404 
42,151 
 
 

 
 
SV-405 
42,151 
 
 

 
 
SV-406 
210,000 
 
 

 
 
SV-407 
210 
,000 
 
 


 
SV-500 
30,618 
 
 
 

 
SV-501 
259,723 
 
 
 

 
SV-502 
442,780 
 
 
 

 
SV-503 
30,000 
 
 
 

 
SV-504 
30,000 
 
 
 

 
SV-505 
30,000 
 
 
 

 
SV-506 
30,000 
 
 
 

 
SV-600 
42,151 
 

 
 
 
SV-601 
42,151 
 

 
 
 
Propane 
 

 
 
 
 
Cavern 
8,000,000 
 
 
 
 
 
Butane 
 
 

 
 
 
Cavern 
3,000,000 
 
 
 
 
 
 
 
 
TABLE 2 
PRODUCT SUMMARIES 
MarkWest Hydrocarbon, Inc. 
Siloam Facility 
South Shore, Kentucky 
PROPANE 
 
 
 
NORMAL  BUTANE 
 
 
 
 
Capacity 
 
 
 
 
 
 
Tank ID 
(gallons) 
(pounds) 
 
 
 
 
 
SV-204 
59,582 
250,244 
 
 
Capacity 
 
 
SV-205 
59,672 
250,622 
 
Tank ID 
(gallons) 
(pounds) 
 
SV-200* 
57,707 
242,369 
 
SV-300 
32,133 
157,452 
 
SV-201 
57,744 
242,525 
 
SV-301 
32,122 
157,398 
 
SV-202 
57,671 
242,218 
 
SV-600 
42,151 
206,540 
 
SV-203 
57,754 
242,567 
 
SV-601 
42,151 
206,540 
 
Propane 
 
 
 
Butane 
 
 
 
Cavern 
8,200,000 
34,440,000 
 
Cavern 
3,000,000 
14,700,000 
 
 
 
 
 
 
 
 
 
Total 
8,550,130 
35,910,546 
 
Total 
3,148,557 
15,427,929 
 
 
 
 
 
 
 
 
 
ISOBUTANE 
 
 
 
NATURAL GASOLINE 
 
 
 
 
Capacity 
 
 
 
Capacity 
 
 
Tank ID 
(gallons) 
(pounds) 
 
Tank ID 
(gallons) 
(pounds) 
 
SV-400 
15,155 
74,260 
 
SV-50 

30,618 
171,461 
 
SV-401 
26,950 
126,665 
 
SV-501 
259,723 
1,454,449 
 
SV-402 
30,000 
141,000 
 
SV-502 
442,780 
2,479,568 
 
SV-403 
42,151 
198,110 
 
SV-407 
210,000 
1,176,000 
 
SV-404 
42,151 
198,110 
 
SV-503 
30,000 
168,000 
 
SV-405 
42,151 
198,110 
 
SV-504 
30,000 
168,000 
 
SV-406 
210,000 
987,000 
 
SV-505 
30,000 
168,000 
 
SV-407 
210,000 
987,000 
 
SV-506 
30,000 
168,000 
 
 
 
 
 
 
 
 
 
Total 
618,558 
2,910,255 
 
Total 
1,063,121 
5,953,478 
 
 
 
 
 
 
 
 
 
Y-GRADE 
 
 
 
 
 
 
 
 
Capacity 
 
 
 
 
 
 
Tank ID 
(gallons) 
(pounds) 
 
 
 
 
 
SV-104 
30,000 
144,000 
 
 
 
 
 
SV-103 
30,000 
144,000 
 
 
 
 
 
SV-102 
18,000 
86,400 
 
 
 
 
 
SV-101 
18,000 
86,400 
 
 
 
 
 
SV-100 
60,000 
288,000 
 
 
 
 
 
 
 
 
 
 
 
 
 
Total 
156,000 
748,800 
 
 
 
 
 
* SV-200 used as storage of natural gas liquids when needed. 
 
The total quantity of product stored in each of the above ground vessels is administratively controlled to ensure that the vessels are not filled above 90% of full capacity.  Additionally, pressure relief devices are installed on the vessels to provide added assurance that the vessels ar 
e not overfilled.  These controls are in place to prevent over-pressurization which could cause structural damage to the vessels and lead to a release.  Based on the administrative controls described above, the maximum product inventories are provided below: 
 
1. The maximum inventory of propane at the facility is:        35,763,491 pounds (lbs.). 
2. The maximum inventory of normal butane at the facility is:    15,355,136 lbs. 
3. The maximum inventory of isobutane at the facility is:        2,619,229 lbs. 
4. The maximum inventory of natural gasoline at the facility is:    5,358,130 lbs. 
5. The maximum inventory of Y-grade at the facility is:        673,920 lbs. 
 
3.    The Worst Case Release Scenario and Alternative Release Scenario, 
including administrative controls and mitigation measures in place to limit the distance for each reported scenario 
 
The parameters of the offsite consequence analyses for this MarkWest facility were based on the requirements set forth in the RMP rules outlined in 40 CFR 68.25 (e), Wo 
rst-case release scenario-flammables  and 40 CFR 68.28, Alternative release scenario analysis.  The worst case and alternative case radii of effect were determined utilizing RMP*Comp software provided by the EPA.  The following describes details of the chosen scenarios. 
 
The worst case scenario for Program 3 flammable substances as a class involves a catastrophic release from the underground propane storage cavern.  The scenario involves the release of the entire quantity of the cavern, approximately 8.2 million gallons (34.44 million pounds) of propane.  It is assumed that the entire quantity is released as a vapor, which finds an ignition source, with 10 percent of the released quantity participating in a vapor cloud explosion.  Under worst case weather conditions (wind speed of 3.4 miles per hour), the maximum distance of 2.63 miles is obtained corresponding to an endpoint of 1 pound per square inch (psi) overpressure.  
 
Utilizing Landview III and Marplot software, the worst case sc 
enario radius of 2.63 miles is illustrated in the graphic file "siloamwc.jpg" (electronic version) and in the attached map (provided in non-electronic versions only).  Major industrial facilities located within this radius include North American Refractories, New Boston Coke, and OSCO Industries.  Residential areas located within the radius include South Shore, Kentucky, New Boston, Ohio, and portions of Portsmouth and Sciotoville, Ohio.  Based on Landview III 1990 census data utilizing the block group proration method, 2,544 households and 6,353 people are located within the 2.63 mile radius.  Finally, eight schools are located within the 2.63 mile radius: Mckinley Middle, Highland Elementary, Wilson Elementary, Oak Street Elementary, Glenwood High, Stanton Elementary, Mckell Middle, and Mckell Elementary. 
 
The alternative release scenario submitted for Program 3 flammable substances involves a release from one of the vessels in the propane storage process.  Vessel SV-200 was arbitrar 
ily selected for use in this scenario.  The scenario involves the release of the entire quantity of the vessel, approximately 51,936 gallons (218,132 lbs) of propane (this quantity is 90% of the entire available capacity of the vessel).  It is assumed that the entire quantity is released as a vapor, which finds an ignition source, with 10 percent of the released quantity participating in the vapor cloud explosion.  Under neutral weather conditions (wind speed of 6.7 miles per hour), the maximum distance of 0.3 miles is obtained corresponding to an endpoint of 1 psi overpressure.  
 
The alternative case scenario radius of 0.3 miles is illustrated in the attached map (provided in non-electronic versions only).  No major industrial or residential areas are located within this radius.  No schools are located in this area.  The radius of effect of this alternative release scenario would remain within the boundaries of MarkWest-owned property.  
 
4.    The General Accident Release Prevention Prog 
ram and the Chemical-Specific Prevention  
   Steps 
 
MarkWest has taken all the necessary steps to comply with accidental release prevention requirements sets out under 40 CFR Part 68 of the EPA regulations.  The propane, normal butane, isobutane, natural gasoline, and NGL storage and distribution processes at MarkWest are subject to the Occupational Safety and Health Administration (OSHA) Process Safety Management (PSM) standard under 29 CFR 1910.119. 
 
The following briefly describes the elements of the release prevention program in place at the MarkWest stationary source. 
 
Process Safety Information 
 
MarkWest maintains a detailed record of written safety information that describes the chemical hazards, operating parameters, and equipment designs associated with all processes. 
 
 
 
Process Hazard Analysis 
 
MarkWest conducts comprehensive studies to ensure that the hazards associated with the processes at the facility are identified and controlled efficiently.  The "What If?" methodology is 
used to carry out these analyses.  The studies are undertaken by a team of qualified personnel in engineering and process operations and are revalidated at regular intervals.  Any findings related to the hazard analyses are addressed in a timely manner. 
 
Operating Procedures 
 
For the purpose of safely conducting activities within covered processes, MarkWest maintains written operating procedures.  These procedures address various modes of operation such as initial start up, normal operations, temporary operations, emergency shutdown, normal shutdown, and startup after turn around.  The information is regularly reviewed and is readily accessible to operators involved with the process. 
 
Training 
 
MarkWest has a comprehensive training program in place to ensure that the employees operating processes are completely competent in the operating procedures associated with the processes.  New employees receive basic training in process operations followed by on-the-job supervision until they a 
re deemed competent to work independently.  Refresher training is provided as needed. 
 
Mechanical Integrity 
 
The integrity of mechanical operations at MarkWest is ensured through documented maintenance checks on process equipment.  Process equipment examined by these checks include among others: pressurized storage vessels, piping systems, relief and vent systems, emergency shutdown systems, controls, and pumps.  Maintenance operations are carried out by qualified personnel with previous training in maintenance practices.  Furthermore, these personnel are offered specialized training as needed.  Any equipment deficiencies identified by the maintenance checks are corrected in a safe and timely manner. 
 
Management of Change 
 
Written procedures are in place at MarkWest to manage changes in process chemicals, technology, equipment, and procedures.  Process operators, maintenance personnel, or any other employees whose job tasks are affected by a modification in process conditions are promp 
tly made aware of and are trained on the specifics of the modification. 
 
Pre-Startup Reviews 
 
Pre-startup safety reviews related to new processes and to modifications in established processes are conducted as required.  These reviews are conducted to confirm that construction, equipment, operating, and maintenance procedures are suitable for safe startup prior to placing equipment into operation. 
 
Compliance Audits 
 
MarkWest conducts audits on a regular basis to determine whether the  provisions set out under the RMP rule are being implemented.  These audits are carried out every three years as required by RMP regulations (40 CFR 68.58) and any corrections required as a result of the audits are undertaken in a safe and timely manner. 
 
Incident Investigation 
 
MarkWest investigates any incident that has resulted in, or could reasonably result in a catastrophic release of a regulated substance.  These investigations are undertaken to identify the situation leading to the incident, as well 
as any corrective actions needed to prevent the release from reoccurring.  All reports are retained for a period of five years. 
 
Employee Participation 
 
MarkWest believes that successful PSM and accident prevention programs require a team effort.  Company employees are encouraged to express their views concerning accident prevention issues and to recommend improvements.  In addition, MarkWest employees have access to all information created as part of the facility's implementation of the RMP program, in particular, information relating to and resulting from process hazard analyses.  
 
Contractors 
 
Periodically, MarkWest hires contractors to conduct specialized maintenance and construction activities.  Prior to selecting a contractor, a thorough evaluation of the safety performance of the contractor is undertaken.  MarkWest has a strict policy of informing contractors of known potential hazards relating to the contractor's work and the associated processes.  Contractors are also informe 
d of all procedures for emergency response should an accidental release of a regulated substance occur. 
 
5.    Five Year Accident History 
 
MarkWest has had an excellent record of preventing accidental releases over the last five years.  Due to stringent release prevention policies, there have been no accidental releases during this period. 
 
6.    Emergency Action Plan 
 
A written emergency action plan to deal with accidental releases of regulated substances is retained at the MarkWest facility.  The plan includes all aspects of emergency response including medical treatment, evacuations, and notification of local emergency response agencies and the public. 
 
To ensure proper functioning, our emergency response equipment is regularly inspected and serviced.  In addition, the plan is promptly updated to reflect any pertinent changes taking place within processes that would require a modified emergency response. 
 
The Scioto County, Ohio and the Greenup County, Kentucky LEPC's are the local emerge 
ncy response agencies with which our emergency plan has been coordinated and verified. 
 
7.    Planned Changes to Improve Safety   
 
One major development has resulted from the implementation of the various elements of this accidental release program: modification of the tank car loading area.  This modification will improve safety at the facility.  This change is expected to occur by December 1999. 
 
8.    Conclusion 
 
MarkWest Hydrocarbon, Inc. has taken all necessary measures required by EPA and OSHA regulations to ensure the continued safe operations of the MarkWest - Siloam facility.  The Risk Management Plan provided herein summarizes the active release prevention program that is currently in place at the facility.  This risk management program illustrates MarkWest's commitment to employee, public, and environmental safety.  In the unforeseeable event that a release does occur, MarkWest's emergency action plan combined with the assistance of the Scioto County, Ohio and the Greenup County,  
Kentucky LEPC's provide assurance that such an event will be successfully and safely mitigated.  
 
 
 
 
 
 
 
 
RISK MANAGEMENT PLAN 
 
MarkWest Hydrocarbon, Inc. 
Siloam Facility 
Route 23 
South Shore - Greenup County, Kentucky 
 
 
 
 
May 26, 1999 
 
 
 
 
 
 
 
 
 
 
Prepared by:                            Reviewed by: 
MARKWEST HYDROCARBON, INC.                MARKWEST HYDROCARBON, INC. 
 
 
                                                    
John Centofanti                            Ron Smith 
Area Environmental Specialist                    Plant Manager 
 
 
 
 
 
 
 
   TABLE OF CONTENTS 
 
 
 
A. EXECUTIVE SUMMARY     1 
 
1. ACCIDENTAL RELEASE PREVENTION AND EMERGENCY RESPONSE POLICIES    .. 1 
 
2. STATIONARY SOURCE AND REGULATED SUBSTANCE HANDLED    . 1 
 
   3. WORST CASE AND ALTENATIVE RELEASE SCENARIOS    4 
 
   4. ACCIDENT RELEASE PREVENTION PROGRAM    5 
 
       a. PROCESS SAFETY INFORMATION    5 
 
       b. PROCESS HAZARD ANALYSIS    6 
 
   c. OPERATING PROCEDURES     6 
 
   d. TRAINING     6 
 
   e. MECHANICAL INTEGRITY     6 
 
   f. MANAGEMENT OF CHANGE     6 
 
   g. PRE-START UP REVIEWS     7 
 
   h. COMPLIANCE AUDITS     7 
 
   i. INCIDENT INVESTIGATION     7 
 
   j. EMPLOYEE PARTICIPATION     7 
 
   k. C 
ONTRACTORS     7 
 
   5. FIVE YEAR ACCIDENT HISTORY    8 
 
   6. EMERGENCY ACTION PLAN    8 
 
   7. PLANNED CHANGES TO IMPROVE SAFETY    8 
 
   8. CONCLUSION    8 
 
 
 
RISK MANAGEMENT PLAN DATA ELEMENTS     ATTACHMENT A 
 
MAPS AND RMP COMP DATA     ATTACHMENT B 
 
Attachment A 
 
RISK MANAGEMENT PLAN DATA ELEMENTS 
 
Attachment B 
 
MAPS AND RMP COMP DATA 
Page 8
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