Callaway Chemical Company - Executive Summary

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24912 LDEQ Facility ID Number 
 
ACCIDENTAL RELEASE PREVENTION AND EMERGENCY RESPONSE POLICIES 
 
The Callaway-Shreveport plant has a long-standing commitment to worker and public safety and to the protection of the environment.  We are committed to operating and maintaining all of our processes in a safe and responsible manner, as demonstrated by the resources we invest to prevent accidents.  As a member of the Chemical Manufacturers Association, we adhere to the principles of Responsible Care..  In addition to ensuring that our employees have the best possible training in the operation of our processes, we demand that safety be the first priority in the design, installation, operation, and maintenance of our processes.  
We have implemented maintenance and inspection programs that ensure site integrity.  Our policy is to implement reasonable controls to prevent foreseeable releases of regulated substances.  Examples of controls to prevent releases include (1) installation of pressure rel 
ief valves to prevent rupture of vessels due to overpressurization, (2) routine visual inspection and thickness checks to ensure vessels and piping are in good condition, (3) using materials of construction that are compatible with the process chemistry, (4) vessel pressure and temperature are continuously monitored and (5) use of carbon scrubbers to remove small amounts of emissions.   
Mitigation measures that have been included in our design include installation of isolation valves, fire suppression systems in areas where flammable chemicals are present and fire fighting equipment in all process areas, a fully implemented emergency response plan, appropriate PPE and an alarm system for early notification of a release.  Since this is a small site, our employees have only been trained to handle fires in the incipient stages and small spills.  We would rely on the local fire department and hazmat team for major spills requiring suit-up. 
 
 
 
STATIONARY SOURCE AND REGULATED SUBSTANCES 
 
The 
Callaway-Shreveport plant is primarily involved in manufacturing paper defoamers and polymers. As a part of this manufacturing process, we use one substance that is covered by the risk management program (RMP) rule (40 CFR 68).  However, we also use a combination of good design practices, an accidental release prevention program, and an emergency response program to ensure the safety of our employees, the public, and the environment.  We are committed to operating our facility in a safe and responsible manner.  Following is a brief description of the facility. 
The Shreveport plant is located on a 5.32 acre site in an industrial park.  The only covered chemical currently is Epichlorohydrin and the maximum storage volume is 105,000 pounds.  This process is subject to Program Level 3. 
 
 
KEY OFFSITE CONSEQUENCE ANALYSIS SCENARIOS 
 
EPAs RMP rule (40 CFR 68) requires that we provide information about two types of offsite consequence analysis scenarios:  worst-case scenarios and alternative 
release scenarios.  There are strict requirements for choosing and modeling worst-case release scenarios; as a result, these scenarios are often exceedingly conservative.  The purpose of the alternative release scenarios is to provide emergency planners with more information about the chemicals we handle and about their relative hazards.  The alternative release scenarios are more realistic than worst-case release scenarios but are still unlikely to happen. 
Following are brief summaries of these scenarios, including information about the key administrative controls and mitigation measures that limit exposure distances. 
Worst-case toxic release scenario 
The worst-case toxic release scenario for Callaway-Shreveport is a catastrophic rupture of a storage tank containing epichlorohydrin.  The entire quantity of epichlorohydrin, 105,000 lb, is released into our containment dike.  The containment dike greatly reduces the offsite effect of the release by limiting the size of the liquid pool  
that results from this spill.  The epichlorohydrin that evaporates from this pool travels approximately 0.40 miles before dispersing below the toxic endpoint. Approximately 50 people live within this distance from the storage tank.  The public and environmental receptors that are located within this distance include: a few houses, one industry and the Logan Bayou Flood zone to Logan's Bayou which eventually flows into Cross Lake. 
Alternative toxic release scenario 
The alternative release scenario for epichlorohydrin is a break in the hose used for unloading epichlorohydrin from a tank truck.  A total of 6,240 lb escapes over a 2-min period before the operator can close the bottom valve and forms a liquid pool on the concrete area surrounding the storage tank.  The epichlorohydrin evaporates from the liquid pool and travels about 0.20 miles before dispersing below the toxic endpoint.  No people live within this distance from the storage tank.  The public and environmental receptors that 
are located within this distance include: only the Logan Bayou flood zone to Logan's Bayou which eventually flows into Cross Lake. 
 
 
GENERAL ACCIDENTAL RELEASE PREVENTION PROGRAM AND CHEMICAL-SPECIFIC PREVENTION STEPS 
 
We take a systematic, proactive approach to preventing accidental releases of hazardous chemicals.  Our management system addresses each of the key features of a successful prevention program, as described below in Sections 4.1 through 4.12. 
 
 
 
PROCESS SAFETY INFORMATION 
 
The Callaway-Shreveport plant maintains a variety of technical documents that describe the chemicals and processes at our facility.  These documents are kept up to date and are available to all employees and address important process parameters such as (1) operating limits for the equipment, (2) design basis and configuration of the equipment, and (3) physical properties and hazards of the chemicals used in our processes. 
Chemical information is usually documented within Material Safety Data Sheets (MS 
DSs). MSDSs contain information concerning both the physical properties and the hazards associated with each chemical.  This information typically includes (1) toxicity information, (2) physical data, (3) reactivity and corrosivity data, (4) thermal and chemical stability data, and (5) hazards of mixing substances together.  MSDSs are available to all employees, as well as the emergency responders in our community.  MSDS's for all Shreveport chemicals are maintained on site. 
Important process parameters are also documented and maintained.  Engineering design documents may include (1) operating limits, (2) block flow or simplified process flow diagrams, (3) process chemistry, (4) maximum intended inventories, (5) design basis and configuration, (6) piping and instrumentation diagrams, and (7) other information that is important for understanding the design intent, operating limits, and hazards of each process. 
 
PROCESS HAZARD ANALYSIS 
 
The Callaway-Shreveport plant has a comprehensive p 
rogram for ensuring that the hazards associated with our processes are identified and controlled.  Each process is examined in detail to ensure that all hazards are identified and that appropriate controls are in place to manage those hazards. 
A hazard and operability (HAZOP) analysis is typically used for our process hazard analyses.  A team comprising personnel with engineering, operations, environmental and maintenance experience systematically examines each hazard in each section of the process and identifies potential causes and a range of possible consequences.  The team then compares the hazard to the existing set of prevention and mitigation measures designed to contain that hazard, making further recommendations when deemed necessary.  These recommendations are resolved by management and are tracked until they are implemented. 
We update and revalidate each process hazard analysis every five years or whenever a significant change is made.  The results and findings from these r 
evalidation studies are documented and retained, and recommendations are tracked until resolved by management. 
 
OPERATING PROCEDURES 
 
Our engineers, operators, and supervisors work together to develop and maintain operating procedures that ensure the safe operation of our facility.  These procedures cover all modes of operation, such as (1) unit startup, (2) normal operations, (3) temporary operations, (4) emergency shutdown, (5) normal shutdown, and (6) initial startup of a new or improved process. Operating procedures are used as a reference by experienced employees and provide a consistent basis for training new employees.  In addition to describing the steps for safely conducting operations, the procedures also contain valuable information about safe upper and lower limits, consequences of deviations, and applicable safety and health information.  Operating procedures are annually certified as accurate to ensure that they are updated following process changes.  
 
The Shreveport plan 
t also operates using the Callaway batchsheet system.  Batchsheets are the detailed operating procedures for making a batch of product.  The batchsheets include process deviation codes describing the actions to take under various conditions (e.g., high temperature, high pressure, loss of cooling, etc) that may be encountered while manufacturing batches using  hazardous chemicals. 
 
TRAINING 
 
The Callaway-Shreveport plant trains workers to safely and effectively perform their tasks.  Employees who are new to a process are given basic training that includes (1) a general overview of the process, (2) the properties of the substances used in the process and their associated hazards, and (3) a detailed review of the operating procedures for that process.  Once they have demonstrated their understanding of this initial training, they are paired with an experienced operator to learn their specific job functions and tasks.  After they demonstrate their competence in performing these tasks, they 
are allowed to work independently. 
Through oral reviews, written tests, and on-the-job demonstration, we ensure that our employees understand the training given to them.  The frequency of refresher training is decided, in part, by our employees but is performed at least every three years.  All training given to an employee is documented, along with the means used to verify that the training is understood. 
 
 
MECHANICAL INTEGRITY 
 
The Callaway-Shreveport plant maintains the mechanical integrity of our equipment to prevent equipment failures that could endanger workers, the public, or the environment.  Our inspection and testing program helps identify equipment damage or deterioration before the equipment fails.  When a deficiency is found, maintenance personnel will correct the problem and try to identify the root causes of the deficiency so that future problems are avoided.  Our quality assurance system ensures that new or replacement equipment meets the strict design standards require 
d for service in our facility.  The mechanical integrity system includes (1) inspection and testing procedures, (2) replacement equipment specifications, (3) procedures for safe work practices, (4) maintenance personnel training, and (5) required documentation. 
 
MANAGEMENT OF CHANGE 
 
We review any changes to our processes to determine if new hazards are introduced or existing prevention measures are threatened.  Except for replacements-in-kind (e.g., replacing a valve with an identical valve), all changes are subjected to a hazard analysis to ensure that (1) new hazards are not inadvertently introduced into the system, (2) safety consequences resulting from the change are addressed, (3) operators in the process are notified of the change and made aware of possible repercussions, and (4) all training material, process safety information, and operating procedures are updated.  The management of change system applies to changes in the chemicals used, process equipment, technology, procedu 
res, and other facility changes. 
 
 
PRE-STARTUP REVIEW 
 
Whenever a change occurs that requires updating the process safety information, the Callaway-Shreveport plant performs a pre-startup safety review.  This review ensures that safety features, procedures, personnel, and the equipment are prepared for service before the process is restarted. A pre-startup review will generally include field verification of new construction and also serves a quality assurance function by verifying that accident prevention measures are implemented correctly.  Generally, a pre-startup review will ensure that (1) construction and equipment are consistent with design standards, (2) adequate operating, safety, and maintenance procedures are in place, (3) training for all affected employees is complete, and (4) a process hazard analysis has been performed, if necessary. 
 
INCIDENT INVESTIGATION 
 
The Callaway-Shreveport plant trains its employees to promptly investigate each incident that resulted in, or could 
have resulted in, serious injury to employees, the public, or the environment.  Incident investigations are designed to determine the facts, identify the root causes, and provide recommendations for ensuring that the incident does not recur.  Corrective actions resulting from an incident investigation are tracked until they are resolved. 
Incident investigations are conducted in accordance with Callaway Safety Standard 201 and utilize Non-Conformance Notices (NCN's) that are defined through our ISO Problem Elimination System (AP-010). 
 
 
EMPLOYEE PARTICIPATION 
 
The Callaway-Shreveport plant encourages employees to be involved in every aspect of process safety management and accident prevention.  Employees are routinely asked to participate in process hazard analyses, incident investigations, management of change hazard analyses, and all other aspects of the prevention program.  Employees have access to all information developed as part of the prevention program, and are specifically inf 
ormed of any changes that occur in their process areas.  The various ways employees are involved in the prevention program are documented in a written plan. 
 
SAFE WORK PRACTICES 
 
The Callaway-Shreveport plant has established safe work practices that ensure the safety of our employees.  Examples of these procedures include (1) a hot work permit that is designed to control spark- or flame-producing activities, (2) a permit and procedure to control confined space entry, and (3) a lockout/tagout procedure for isolating energy sources during maintenance.  These procedures and permits ensure that operations and maintenance activities are performed safely. 
 
CONTRACTORS 
 
The Callaway-Shreveport plant uses contractors for various activities, such as maintenance and construction. All contractors are evaluated to ensure that they are well trained and are able to perform their job function in a safe manner.  A contractors safety record and performance are reviewed during the selection process. 
On 
ce a contractor is selected, the Callaway-Shreveport plant provides training and procedures to ensure that contractor employees (1) perform their work in a safe manner, (2) are aware of the hazards associated with the area in which they will be working, (3) understand the emergency response procedures, and (4) report any hazards they find during their work.  Our personnel periodically monitor contractor activities to ensure they are performing their work in a safe manner. 
 
COMPLIANCE AUDITS 
 
A compliance audit is performed periodically to help ensure that the prevention program activities at our facility are adequate and that safety issues are addressed effectively.  Audits are performed by a team that is knowledgeable in our processes, but is independent of our facility, to ensure a thorough and complete evaluation.  The audit team systematically evaluates each aspect of the prevention program, ensuring both compliance with the RMP rule and effective hazard prevention.  The results of 
audits are documented, and recommendations are tracked until they are resolved.  Compliance audits are conducted at least every three years. 
 
CHEMICAL-SPECIFIC PREVENTION STEPS 
 
The prevention program described previously ensures the safe operation of our facility by providing our employees with a system they can use to safely perform their job functions.  This management system helps prevent hazards associated with equipment failures and human error. In addition to the prevention program, the Callaway-Shreveport plant has safety features built into the design of our facility that help to ensure safe process operation for our employees, the public, and the environment.  These features may contain or control a release, detect a release, or reduce the consequences of a release.  They may also prevent a release by providing strict design standards for process equipment.  The following types of safety features are used in various processes in our facility: 
Release detection 
7    Procedures r 
equire that a Callaway-Shreveport plant employee be present during loading and unloading operations 
Release containment and control 
7    Valves to permit isolation of the process 
7    Automated shutdown systems for some process parameters (e.g., high level, high pressure) 
7    Manual shutdown systems located in the control room 
7    Diked areas designed to contain a release 
7    Pressure relief valves and rupture disks that discharge safely to the atmosphere 
Release mitigation 
7    Fire suppression equipment 
7    Trained emergency response personnel 
7    Personal protective equipment (e.g., protective clothing, self-contained breathing apparatus) 
      7    Spill Clean-up equipment 
 
FIVE-YEAR ACCIDENT HISTORY 
 
Our five-year accident history shows that the Shreveport plant has had no accidental releases of epichlorohydrin. 
 
 
EMERGENCY RESPONSE PROGRAM 
 
The Callaway-Shreveport plant relies on our community emergency responders (e.g., the fire department) to mitigate releases from our facility and to notify the 
community.  However, we maintain procedures that address many of the other aspects of an emergency response, such as proper first-aid and other medical procedures and the use of personal protective equipment. 
The Callaway-Shreveport plants emergency response procedures are coordinated with local emergency responders.  The local responders are trained in the hazards of the substances we handle, and communication channels are kept open 24-hours per day.  This coordination and communication ensures that the public is quickly notified, if necessary, and that action is promptly taken to minimize the consequences of a release. 
 
 
PLANNED CHANGES TO IMPROVE SAFETY 
 
The Callaway-Shreveport plant continuously strives to improve the safety of our processes.  Suggestions for improving safety are regularly addressed through process hazard analyses, management of change procedures, incident investigations, and employee suggestions.  
Callaway Chemical has implemented a comprehensive Year 2000 progr 
am that addresses all aspects of computer, microprocessor and software use throughout the company's business and industrial operations.  At the plant, the Year 2000 program addresses computers, microprocessors and software controlling operations of the plant.
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