East Side Wastewater Treatment Plant - Executive Summary

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                      Executive Summary 
 
    Watts Engineers was subcontracted by Pratt and Huth Associates, LLP to provide the 
City of Oswego a Level 3 Risk Management Program (RMP) and a Process Safety Management 
(PSM) Program in  accordance with 40 CFR 68 Risk Management Programs for Chemical 
Accidental Release Prevention and 29 CFR 1910.119 Process Safety Management for it's East 
Side Wastewater Treatment Plant (WWTP) located at 71 Mercer Street in the City of Oswego, 
New York.  This evaluation was performed to assure that the facilities chlorine injection system 
complies with applicable regulations.  Key elements of the Risk Management Plan provided by 
Watts Engineers included:  a review of the accidental release prevention and emergency response 
policies; a review of the regulated substance handled; a worst-case and an alternative release 
scenario; a review of the general accidental release prevention program and chemical-specific 
prevention steps; a review of the five-year acc 
ident history; a review the emergency response 
program; and participation in meetings and planning changes to improve the Process Safety 
Program.   Watts Engineers will electronically submit this Risk Management Plan to the 
Environmental Protection Agency (EPA) by June 21, 1999.   
 
    The Oswego East Side WWTP is located on the East Side of the City of Oswego between 
Fort Ontario to the West and The Hammermill Paper Company to the East .  It employs fourteen 
(14) full-time employees.  Activities at the facility include the treatment of Wastewater, removal 
of solid waste, and the treatment of the water portion with the addition of chlorine gas before 
returning the water to Lake Ontario.   
 
    Chlorine is considered a regulated substance under the Risk Management and Process 
Safety Programs.  Characteristics of this gas or liquid include a pungent suffocating odor.  It is 
irritating to the mucous membranes.  When chlorine reacts with water, it forms hydrochloric 
acid.  Hydrochloric a 
cid gas is a toxic and corrosive fume.  The odor threshold for chlorine is 
about 0.5 ppm.  Long term exposures to small concentrations or short term exposures to high 
concentrations may result in adverse health effects.  Since chlorine gas is heavier then air,  It can 
settle in low spots along the ground, therefore, care should be exercised while working in 
confined spaces or low lying areas.   
 
     The City of Oswego and senior management at the East Side Wastewater Treatment 
Plant have a strong commitment to the overall safety of it's employees, the public, and 
the environment.  It is the policy of the East Side WWTP to train each employee and contractor 
about safety considerations and emergency procedures in the unlikely event of a discharge.  A 
maximum of fourteen thousand (14,000) pounds of chlorine gas in seven (7) tanks gas are either 
used or stored at one time at the facility.  Each tank contains two thousand (2,000) pounds of 
chlorine gas. The chlorine is composed of 99.5 pe 
rcent chlorine and 0.5 percent inert ingredients.  
The tanks are located on a storage pad behind the facility.  The storage pad is covered by a 
canopy constructed of sheets of corrugated steel used for a roof.  The storage area is otherwise 
open to air.  Chlorine is being delivered by truck and unloaded using a two ton crane onto a set of 
steel rails where the gas tank is stored until it is ready for use. Each end of the rails are chocked 
to prevent the gas tanks from rolling.  Each gas tank has it's own valve guard to prevent objects 
from coming in contact with the valves.   
 
    When a chlorine tank is needed, a two ton crane lifts the cylinder and is moved along a 
crane rail through a set of double steel doors and into the tank scale room.  The tank scale room  
is fully enclosed.  The room is labeled "chlorine hazard" and emergency instructions are posted 
at the door.  Material Safety Data Sheets (MSDS) are located in a common hallway by the 
operators station.   
 
     Within the t 
ank scale room is the chlorine injection room.  PVC tubing leads 
from the tanks into the chlorine injection system.  Here, the chlorine is injected into the 
wastewater through a series of valves and PVC tubes. 
 
      The chlorine tanks are stored on to a calibrated scale, designed to hold the four, two 
thousand pound tanks on roller trunnions. The chlorine containers have two valves in each head, 
With the tank in a horizontal position and the valves in a vertical line, they deliver gas from the 
upper valve and liquid from the lower valve.  Five hundred (500) psig copper tubing fitted with a 
special adapter is used to connect the tank to the tubing system.  To connect the line to the 
container, a valve protection hood and the valve outlet cap are removed.  A wrench is used to 
connect the valving to the yoke.  A new gasket, which is supplied with the container is used each 
time a connection is made.  As part of the Process Safety Management Program leaks are then 
checked using ammonia v 
apor.  The appearance of white vapor indicates a chlorine leak.  A 
protective suit, gloves, and a self-contained breathing apparatus (SCBA) are worn by the operator 
and a chlorine tank repair kit are kept on hand in the unlikely event of a chlorine leak while 
changing tanks.  In the past five years, this facility has had no accidental releases of chlorine. 
 
    The City of Oswego East Side Wastewater Treatment plant maintains a general accidental 
release prevention program and chemical specific prevention steps.  As a part of this program, a 
chlorine alarm system is in place at the facility.  The chlorine detector and alarm are located on 
the wall outside of the chlorine injection room.  The chlorine sensors are located in the injection- 
tank scale room.  In the event of a chlorine leak, a audio and visual alarm will sound in the 
operator's control room which is staffed twenty four (24) hours a day, seven days a week.  The 
monitor is maintained and calibrated by an outside contractor. 
The calibration frequency is yearly 
as recommended by the manufacturer.  Literature and information on the alarm system is kept on 
file by the superintendent of the facility.  All employees are trained yearly on the chlorine alarm 
system.  An operator receiving an alarm is to follow the emergency response plan. 
 
    The chlorine injection system itself operates under a vacuum produced by the injector 
mechanism.  Gas leaves the tank through a vacuum regulating valve.  A diaphragm senses 
vacuum on one side and atmospheric pressure on the other.  A spring loaded stem off the seat is 
displaced by force on the diaphragm.  Gas moves toward the flow control components and proper 
vacuum is maintained.  While under vacuum, gas enters the rotameter where it's flow is 
measured.  Gas flow rate is controlled by a v-notch orifice and either manual or automatic 
positioning of the v-grooved plug in it's ring.  A differential regulating valve is located after the 
orifice which maintains the proper va 
cuum across the v-notch.  A pressure-relief valve vents to 
the atmosphere if a malfunction occurs and pressure builds.  Gas is then dissolved in the water 
stream at the injector.  Check valves are in place and designed to close on injector shutdown.  
There are no lines carrying gas under pressure in this system.  Loss of vacuum for any reason 
causes the vacuum regulating valve to shut off the gas supply.   
 
    The facility also complies with the Occupational Safety and Health Process Safety 
Management rule.  Management believes that the training of it's employees and it's contractors is 
crucial to maintaining a safe environment and continuing it's accident-free record for the chlorine 
system.  Training of all employees consists of a general orientation of the chlorine system first.  
They are then instructed on the hazards and proper and safe handling of the chlorine system.  The 
following courses are administered to all employees and refreshed yearly: 
 
    General Safety Training 
 
  DEC Wastewater Operator Renewal Training 
    Hazard Communication Training 
    Confined Space Training 
    Respiratory Protection Program Training 
    Lock-out/Tag-out 
    Chlorine Tank Handling and Connections 
    Hearing Protection Program 
    Personal Protective Equipment Program 
 
A record is kept of the training and placed in the training files.  The record contains the 
employee or contractor name, title of course, date the course was held, name of the trainer, 
and results of any written, oral, or hands-on exam.    
 
    Accidents are also prevented by good administrative controls.  Standard Operating 
Procedures (SOPs) are kept on hand and are easily accessible to the workers.  Each operator is 
trained in the applicable aspects of their job functions.  Those operators whose work is involved 
with any aspect of the chlorine injection system are thoroughly trained in those specific SOPs.  
Workers who need to be inside the chlorine tank scale  room or the chlori 
ne injection room are  
provided chlorine specific training.     
 
    The City of Oswego East Side Wastewater Treatment Plant maintains an Emergency 
Management Program.  In the event of a chlorine leak,  the operator will first notify the other 
employees by sounding a general alarm and then determine the location and magnitude of the 
leak.  The magnitude is broken down to minor leaks; no yellowish gas is visibly present, and 
major leak; yellowish gas is visibly present.  For a minor leak, two trained operators will don 
SCBAs and protective gear and using the ammonia and water vapor bottle, find where the leak is 
and rectify the situation.  In the event of a major leak, the operator will call the Oswego Fire 
department immediately and then notify the other workers in the plant of the major chlorine leak.  
The operator will designate one location that is upwind from the chlorine leak for all personnel to 
assemble and remain until the fire department informs the operator otherwise.  The 

uperintendent will then be called and informed of the situation.  The Oswego Fire Department 
will be in charge of the scene until they depart.  The approximate response time is less than five 
minutes.  
 
    Each member of the fire department is trained to at least HazMat Level I.  Two 
members are trained to the Technician Level, and eleven members are trained to the Specialist 
Level.  The fire department has toured the plant to become familiar with what is on site, and 
develop different leak scenarios and practice emergency response measures.  In June of 1996, a 
HazMat drill with the Fulton Fire Department Haz-Mat Team was conducted.  The Haz-Mat 
Team was activated.  The scenario staged was that a tank while being changed, started leaking.  
A full decon was set up.  The entry personnel used the chlorine kit to stop the tank from leaking.  
A full critique was conducted, and everyone at the scene reviewed the site.  On March  18, 1997, 
seven members of the Haz-Mat Team conducted a drill 
at the treatment plant.  This scenario was 
a leak in the feed line.  The crew followed SOPs to fix the problem.  In August and September 
1997, all four fire department shifts conducted a mock drill of a worker overcome by chlorine 
while in a confined space.  Monitoring equipment,  rigging, and harnesses were used in the entry.  
The fire department also has a chlorine tank simulator that they practice using an  "A" and a "B" 
chlorine tank repair kit on. 
 
    In the attached Risk Management Plan, toxic worst case and toxic alternative release 
scenarios were examined.  The scenarios were developed based on a two-thousand pound tank 
filled with 99.5 percent chlorine.  The quantity released was the full two thousand pounds at a 
release rate of two hundred pounds per minute for ten minutes.  The meteorological factors were 
an atmospheric stability class of "F" and a wind speed of 1.5 meters per second.  The topography 
is urban.  The release is assumed to be at ground level.  The toxic endp 
oint is 0.0087mg/L 
(3ppm).  These airborne concentrations are the maximum airborne concentrations that most 
people can be exposed to for up to one hour without experiencing serious or irreversible effects 
or symptoms.  The calculated distance to endpoint is 1.3 miles. 
 
      The alternate release scenario for the chlorine injection system is one that is more likely 
to occur than the worst case scenario that reaches an end point off-site.  A chlorine leak caused 
by piping or valve failure is used in the alternative scenario.  A hole diameter of 1/4 inch on the 
piping or valve could theoretically occur.  The release rate for this scenario is 9 pounds per 
minute for 222.2 minutes.  The meteorological conditions were atmospheric stability class of "D" 
and a wind speed of 3.0 meters per second.  The topography is urban.  Again the toxic endpoint 
is 0.0087 mg/L (3 ppm).  The calculated distance to endpoint for the alternative scenario is 0.10 
miles.  Methodology for determining distance to  
endpoints was done by referencing Risk 
Management Program Guidance for Wastewater Treatment Plants (40 CFR Part 68).  
 
    The chemical of concern at the East Side Wastewater Treatment Plant is chlorine.  
Chlorine can be toxic if not handled properly, however, the City of Oswego has a reasonable 
program in place to minimize the potential risks to a chlorine gas release.  A training program 
combined with required recordkeeping, administrative controls, an effective emergency 
management program, a local HazMat team, and an alarm system all address and meet the needs 
of the applicable regulations as defined under 40 CFR 68 and 29 CFR 1910.119.  The East Side 
Wastewater Treatment Plant is currently evaluating improvements to their safety program.  They 
are investigating expanding the area that the chlorine sensors monitor along with visual, as well 
as audio alarms.  They are also taking this opportunity to improve and expand their training 
programs, to make their employees further aware o 
f the continued necessity for the safe use of 
chlorine.  
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