Lyondell ACN Railcar at UCC Massey Railyard - Executive Summary

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LYONDELL CHEMICAL COMPANY 
MASSEY RAILYARD 
RISK MANAGEMENT PLAN 
 
EXECUTIVE SUMMARY 
 
 
 
 
NOTE:  Lyondell has determined that there is a possibility that the Massey Railyard is not covered by the RMP regulations.  Lyondell has asked the EPA to make an official determination on the applicability of the RMP regulations to the Massey Railyard.  As of June 21, 1999, Lyondell has only received conflicting individual opinions from EPA personnel and is still waiting to receive the official EPA determination. 
 
Therefore, we are filing a Risk Management Plan for the Massey Railyard in case the official determination indicates that Massey Railyard is covered by RMP. 
 
 
Introduction: 
 
HISTORY 
 
Lyondell Chemical Company, one of the world's largest chemical companies, is comprised of wholly owned businesses operating under the Lyondell name and major ownership positions in Equistar Chemicals, LP, Lyondell-Citgo Refining LP and Lyondell Methanol Company, LP.  In 1998, Lyondell acquired the assets of ARCO 
Chemical Company (ACC), including the facilities in South Charleston and Institute, West Virginia.  These facilities are located within the existing Union Carbide Corporation's South Charleston plant, and within the Rhone-Poulenc plant in Institute. Also included in this acquisition were urethanes research and development facilities located within the Union Carbide South Charleston Technical Center. 
 
Worldwide, the Lyondell enterprise operates in 15 countries, has approximately 11,000 employees, and consists of businesses with more than $17 billion in assets.  In West Virginia, Lyondell directly employs about 135 people and provides employment for about 135 people under contract from Union Carbide and Rhone-Poulenc.  
 
 
 
PRODUCTS 
 
The Lyondell enterprise produces quality chemicals, polymers, and refined petroleum products that form the basis for plastics and synthetics of all kinds.  Products made from these materials fill the supermarket shelves and go into automobiles, housing, cloth 
ing and other necessities that improve the quality of life by making products safer, healthier and more convenient. 
 
The products made at our West Virginia facilities belong to a family of chemicals called polyether polyols, and are derived from a chemical called propylene oxide, which is supplied by other Lyondell plants on the Gulf Coast. Polyols are used primarily in polyurethane foams for products ranging from bedding and furniture, to automotive applications such as seat 
cushions and energy absorbing instrument panels and side panels. Nearly two-thirds of all the auto seats in the U.S. today are made using the Lyondell polyols products from the Kanawha Valley. Other polyols products we make here are used by our customers for applications as diverse as roof coatings, varnishes, roller blade wheels, and bowling balls.  All of the products are shipped to customers in other states or are exported to Europe, Asia, and South America. 
 
Another product from our West Virginia facilities is 
technology. The scientists and technicians at our South Charleston Technical Center work closely together with our manufacturing organization here to develop new or improved polyols products and process technologies. These new technologies can then be used by other Lyondell polyols manufacturing sites around the world. 
 
 
RESPONSIBLE CARE. 
 
Lyondell Chemical Company is fully committed to the principles of Responsible Care, which is an initiative of the Chemical Manufacturers Association (CMA) to improve industry performance in the areas of environment, health and safety, to improve the industry's safe management of chemicals, and to respond to public concerns.  Since 1990, emissions of hazardous chemicals to the air from the Lyondell West Virginia facilities have been reduced by over 90% through improving processes and eliminating inefficient operations.  We have also made continuous improvements in our safety performance every year and rank among the industry leaders in this important 
aspect.  It is a policy of Lyondell to establish goals for continuous improvement in the areas of health, safety, and the environment based on sound science, risk assessment and benefit analysis, against which we will measure, audit and communicate our performance. 
 
Another initiative for continuous improvement is called Manufacturing Excellence.  Manufacturing Excellence, launched in 1991, is a program of corporate standards which incorporates all of the Responsible Care.  codes and Lyondell's own rigorous management systems.  Manufacturing Excellence incorporates a system of Manufacturing Excellence Standards which ensure superior performance and continuous improvement in the following five key areas: safety and health, environmental, product quality, manufacturing reliability, and efficiency.  The Manufacturing Excellence System consists of 43 performance standards in the five key areas listed above, and a system of Lyondell Facility Audits and Third Party Audits to evaluate compli 
ance with the performance standards.  The Third Party Audit System evaluates the regulatory compliance, reliability, and liability associated with the following types of third parties:  Waste Sites, Terminals, Tollers, Key Suppliers, and Transporters.  A rigorous auditing process evaluates how well our facility is meeting the high standards of Manufacturing Excellence.  Audit teams composed of experts from various Lyondell facilities and the corporate auditing department examine performance, site conditions, and documentation to make sure the Manufacturing Excellence standards are met. 
 
 
I. Accidental Release Prevention and Emergency Response Policies 
Lyondell has a contract with Union Carbide Corporation to use the Union Carbide Massey Railyard to stage and store chemical raw material railcars until they are needed in the Lyondell South Charleston Plant.  Lyondell has a contract with Union Carbide to obtain emergency response services from the Union Carbide South Charleston Plant Emer 
gency Response Team.  The South Charleston Plant provides emergency response services to the Union Carbide Massey Railyard.   
 
The Union Carbide South Charleston Massey Railyard is committed to storing chemical railcars in a safe and responsible manner.  Union Carbide and Lyondell have implemented a combination of accidental release prevention programs and emergency response planning programs to help ensure the safety of our employees and the public, as well as to protect the environment.  These programs include Lyondell's Manufacturing Excellence requirements, Union Carbide's Responsible Care. requirements, and governmental requirements, such as the Environmental Protection Agency's (EPA) Risk Management Program (RMP) rule (40 CFR Part 68) and the Occupational Safety and Health Administration's (OSHA) Process Safety Management (PSM) Standard (29 CFR Part 1910.119).  This document is intended to satisfy the RMP Plan requirements of the RMP rule and to provide the public with a descript 
ion of the risk management program at the facility. 
 
 
II. STATIONARY SOURCE AND REGULATED SUBSTANCES 
NOTE:  Lyondell has determined that there is a possibility that the Massey Railyard is not covered by the RMP regulations.  Lyondell has asked the EPA to make an official determination on the applicability of the RMP regulations to the Massey Railyard.  As of June 21, 1999, Lyondell has only received conflicting individual opinions from EPA personnel and is still waiting to receive the official EPA determination. 
 
Therefore, we are filing a Risk Management Plan for the Massey Railyard in case the official determination indicates that Massey Railyard is covered by RMP. 
 
 
The Massey Railyard is owned by Union Carbide Corporation (UCC) and is separated from the South Charleston Plant by the CSX Railroad property. The Union Carbide Massey Rail Yard is used to temporarily store tank cars for eventual processing at the South Charleston Plant. The rail yard is managed by the South Charleston P 
lant, but is not considered contiguous by EPA definition with the South Charleston Plant. The CSX Railroad property sits between the Massey Railyard and the South Charleston Plant. No chemical unloading takes place at the Massey Rail Yard.  Lyondell has a contract with Union Carbide Corporation to use the Union Carbide Massey Railyard to store chemical raw material railcars until they are needed in the Lyondell South Charleston Plant.   
 
ACN is a chemical raw material used to make certain grades of Polyether Polyols.  Lyondell  stores railcars containing acrylonitrile (ACN) at the Union Carbide Massey Railyard.  An ACN Supplier owns the ACN Railcar(s) and Lyondell owns the ACN material inside the ACN Railcar(s) once it is placed into the Massey Railyard by CSX.  CSX delivers the ACN Railcar(s) to the Massey Railyard for a storage period of 1 to 30 days.  Once CSX places the ACN Railcar(s) in the Massey Railyard, the ACN Railcar(s) is no longer under active shipping papers.  Upon reques 
t from Lyondell and UCC, CSX transfers the ACN Railcar(s) from Massey Railyard, through the CSX Railroad property, onto the South Charleston Plant to the Lyondell ACN Unloading Station within the South Charleston Plant.  The South Charleston Plant is owned by UCC, Lyondell is a tenant in the facility, and Lyondell leases part of the South Charleston Plant for its operations.  Lyondell stores 1 to 7 ACN Railcars at the Massey Railyard during a typical month.  The South Charleston Plant is covered under the RMP Regulations.  Lyondell and UCC store and use RMP regulated chemicals at the South Charleston Plant.  The South Charleston Plant facilities of both Lyondell and UCC are covered by the RMP Program Level 3.   
 
There are no Lyondell employees located at the Union Carbide Massey Railyard.   
 
The polyols we make at the South Charleston Plant and the Institute Plant are used by our customers to manufacture polyurethane foams for such applications as furniture cushions, mattresses, and fo 
r automotive applications such as seat cushions and energy absorbing instrument panels and side panels. Other customer applications include various coatings, adhesives, sealants, and elastomers.  
 
Lyondell stores an RMP-regulated toxic substance at the Union Carbide Massey Railyard in sufficient quantity to be covered by the RMP rule.  
 
Lyondell stores threshold quantities of the following RMP-regulated toxic substance at the Union Carbide Massey Railyard: 
    
7 Acrylonitrile  
 
 
Lyondell does not handle, process, or store threshold quantities of any RMP-regulated flammable chemicals at the Union Carbide Massey Railyard. 
 
 
III. Offsite Consequence Analysis Scenarios 
 
The Risk Management Program rule requires that covered stationary sources handling regulated substances conduct off-site consequence analyses (OCA) to evaluate the potential off-site impact of a worst-case scenario (WCS) and an alternative release scenario (ARS) for each regulated toxic chemical on site.  RMP also requires co 
vered sources to evaluate one worst-case scenario and one alternative release scenario for a single chemical representing the class of flammables.   
 
All of these scenarios are developed using guidelines established in the RMP rule.  In developing worst-case scenarios, companies must presume the release of the entire quantity of the largest container of a regulated chemical over a 10-minute period.  Only passive mitigation systems, such as those that do not require energy or action by an employee to initiate can be considered.  U.S. EPA acknowledges that these worst-case scenarios are unlikely to occur, so the RMP rule also requires that companies develop alternative release scenarios based on more credible release assumptions.  
 
Alternative release scenarios differ from worst-case scenarios in several important ways.  They may be based on actual incident history or on events which are more likely to occur, and allow the use of both active and passive mitigation to reduce the potential 
impact of a release on the community outside the facility. 
 
EPA's Off-Site Consequence Analysis (OCA) Guidance Tables were used for evaluating the consequences of the WCS and ARS for both regulated flammable and toxic materials.  Use of these tables resulted in the determination of a release endpoint distance. The EPA-recommended LANDVIEW program was used to estimate the number of people potentially affected in each scenario.  The West Virginia Kanawha/Putnam County Emergency Services Maps and CD-ROM Program were utilized to identify the public and environmental receptors located within the scenario endpoint distance. 
 
According to the RMP rule, the release endpoint distance is intended to provide an estimate of the maximum possible area that might be affected for each scenario.  It is intended to ensure that potential risks to the public health are recognized.  For toxic releases, the endpoint is the distance beyond which chemical concentrations are low enough that an average individ 
ual could be exposed for up to one hour without suffering irreversible or debilitating health effects.   For flammable releases, the endpoint distance is that distance beyond which the community would be subject to a pressure wave of less than 1 psi resulting from the formation of an exploding vapor cloud.  Below this value little or no impact to the community is expected. 
 
The RMP rule requires that we provide information about the worst case and alternative case scenarios in our facility Risk Management Plans.  The following are brief summaries of these hypothetical scenarios.  Unless otherwise specified, no credit was taken for administrative controls or mitigation measures in the worst case scenarios. However, chemical-specific steps that would likely be taken to prevent or mitigate the effects of each scenario are listed immediately following the scenario description. The alternative release scenario descriptions include those mitigation measures that were considered, and any meas 
ures for which credit was not taken are listed.  More information on the facility's general accident prevention program is described in Section IV. 
 
 
A)  Regulated Toxic Substances 
 
1. Worst Case Scenario(s) 
 
1.1  Worst Case Scenario - acrylonitrile  
 
The worst case scenario for acrylonitrile assumes a catastrophic failure of the acrylonitrile railcar, releasing 190,000 pounds of acrylonitrile as a liquid, leading to a vapor cloud release.  According to EPA's Off-Site Consequence Analysis (OCA) Guidance Table, this release could impact off-site public receptors. 
 
No passive mitigation measures were used in this analysis. 
 
This worst case scenario does not allow credit to be taken for the following safety and prevention systems which are in place to prevent this scenario from occurring, and to mitigate its effects should it occur:  
 
7 Safety Relief Valve:  A pressure relief valve which relieves at excessive pressure to prevent a railcar overpressure and rupture. 
7 Department of Transpor 
tation / Federal Railroad Administration:  Requirements for special leak detection procedures and plugging of vents and drains to contain leaks or releases.  
7 Dedicated Railcars:  Railcars are dedicated for acrylontrile storage only.  This avoids cross-contamination with other chemical materials and ensures proper equipment setup (safety relief device sizing, specific gasket material, specific transfer line fittings, etc.) 
7 No Bottom Valves:  There are no bottom valves on the acrylonitrile railcars, and all transfers and unloading is done through a transfer line on the top of the railcar.  This prevents any leaks, drips, or releases from the bottom of the railcar and prevents spills during transfer or unloading operations.  
7 Cameras:  The acrylonitrile railcar is under surveillance by area cameras that are watched from a main control room.  This is in addition to the field surveillance. 
7 Fire Water Spray Monitors:  A water spray system that knocks down acrylonitrile vapors to limit 
and control any vapor release.  
7 Vendor Railcar Tracking System:  The acrylonitrile vendor uses a proprietary railcar tracking system to track the location and condition of each loaded and empty acrylonitrile railcar.  The vendor provides periodic reports from this railcar tracking system to Lyondell.    
7 Vendor Railcar Mechanical Integrity Program:  The acrylonitrile vendor has a Mechanical Integrity Program for testing, inspection, and maintenance of the acrylonitrile railcars.  This program ensures the structural integrity of the railcar tank and supporting devices such as valves, gaskets, pressure relief devices, hoses, instruments, and coupling systems. 
7 Surveillance: Railyard operating employees, security personnel, and RESCAR employees make routine unit walk-throughs to make sure the railcars are secure and all safety equipment and systems are operating properly. 
7 Lyondell Railcar Tracking System (RTMS):  Lyondell uses a proprietary railcar tracking system called Railcar Tr 
ip Management System (RTMS).  This railcar tracking system provides daily reports on the location, condition, status, product, freight weight, destination, carrier, etc., for acrylonitrile supplier railcars.     
7 Vendor Emergency Response Systems:  The acrylonitrile vendor has various emergency response systems for responding to any railcar incident nationwide as needed. 
7 Railroad Transportation Notification and Coordination:  The CSX Railroad Company provides notification and coordination for all acrylonitrile railcars to ensure proper transportation, consignment, movement, and placement.  CSX verifies proper execution of all placement instructions. 
7 Weighmaster Training/Certification:  A formal training, testing and certification program that ensures proper skill and knowledge prior to independently handling the railcars.  This program requires weighmasters to be trained to inspect, load and unload railcars.  
 
 
 
2. Alternative Release Scenario(s) 
 
2.1 Alternative Release Scenario  
- acrylonitrile 
 
The alternative release scenario for acrylonitrile assumes a weld fatigue failure causing a 0.196 inch hole in the railcar tank shell, releasing 948 pounds of acrylonitrile, during a 60-minute period, as a liquid, leading to a vapor cloud release.  This scenario assumes a release rate of 15.8 pounds per minute for 60 minutes.  According to EPA's Off-Site Consequence Analysis (OCA) Guidance Table, this release could impact off-site public receptors. 
 
No passive mitigation measures were used in this analysis. 
 
The following active mitigation measures were used in this analysis: 
7 Surveillance: Railyard operating employees, security personnel, and RESCAR employees make routine unit walk-throughs to make sure the railcars are secure and all safety equipment and systems are operating properly.  
7 Cameras:  The acrylonitrile railcar is under surveillance by area cameras that are watched from a main control room.  This is in addition to the field surveillance. 
7 Railroad Tran 
sportation Notification and Coordination:  The CSX Railroad Company provides notification and coordination for all acrylonitrile railcars to ensure proper transportation, consignment, movement, and placement.  CSX verifies proper execution of all placement instructions. 
 
This scenario assumes that the leak is detected and stopped over a 60-minute period due to security guard surveillance, monitoring the area cameras, and coordination with CSX Railroad Company.   
 
This alternative release scenario does not allow credit to be taken for the following safety and prevention systems which are in place to prevent this scenario from occurring, and to mitigate its effects should it occur:  
 
7 Safety Relief Valve:  A pressure relief valve which relieves at excessive pressure to prevent a railcar overpressure and rupture. 
7 Department of Transportation / Federal Railroad Administration:  Requirements for special leak detection procedures and plugging of vents and drains to contain leaks or releas 
es.  
7 Dedicated Railcars:  Railcars are dedicated for acrylontrile storage only.  This avoids cross-contamination with other chemical materials and ensures proper equipment setup (safety relief device sizing, specific gasket material, specific transfer line fittings, etc.) 
7 No Bottom Valves:  There are no bottom valves on the acrylonitrile railcars, and all transfers and unloading is done through a transfer line on the top of the railcar.  This prevents any leaks, drips, or releases from the bottom of the railcar and prevents spills during transfer or unloading operations.  
7 Fire Water Spray Monitors:  A water spray system that knocks down acrylonitrile vapors to limit and control any vapor release.  
7 Vendor Railcar Tracking System:  The acrylonitrile vendor uses a proprietary railcar tracking system to track the location and condition of each loaded and empty acrylonitrile railcar.  The vendor provides periodic reports from this railcar tracking system to Lyondell.    
7 Vendor Rai 
lcar Mechanical Integrity Program:  The acrylonitrile vendor has a Mechanical Integrity Program for testing, inspection, and maintenance of the acrylonitrile railcars.  This program ensures the structural integrity of the railcar tank and supporting devices such as valves, gaskets, pressure relief devices, hoses, instruments, and coupling systems. 
7 Lyondell Railcar Tracking System (RTMS):  Lyondell uses a proprietary railcar tracking system called Railcar Trip Management System (RTMS).  This railcar tracking system provides daily reports on the location, condition, status, product, freight weight, destination, carrier, etc., for acrylonitrile supplier railcars.     
7 Vendor Emergency Response Systems:  The acrylonitrile vendor has various emergency response systems for responding to any railcar incident nationwide as needed. 
7 Weighmaster Training/Certification:  A formal training, testing and certification program that ensures proper skill and knowledge prior to independently handlin 
g the railcars.  This program requires weighmasters to be trained to inspect, load and unload railcars.  
 
 
 
 
B)  Regulated Flammable Substances 
 
Lyondell does not handle, process, or store threshold quantities of any RMP-regulated flammable chemicals at the North Charleston Distribution Terminal. 
 
 
 
 
 
 
 
IV. General Accidental Release Prevention Program and Chemical-Specific Prevention Steps 
 
General Program 
 
The Lyondell West Virginia general accident prevention program consists of compliance with the EPA RMP rule and the OSHA PSM standard, and implementation of Lyondell's Manufacturing Excellence Standards, Union Carbide's Operational Safety Program and Union Carbide's Episodic Risk Management System.   
 
The key elements of these systems include the following: 
 
Safety Relief Valve:  A pressure relief valve which relieves at excessive pressure to prevent a railcar overpressure and rupture. 
Department of Transportation / Federal Railroad Administration:  Requirements for special leak de 
tection procedures and plugging of vents and drains to contain leaks or releases.  
Dedicated Railcars:  Railcars are dedicated for acrylontrile storage only.  This avoids cross-contamination with other chemical materials and ensures proper equipment setup (safety relief device sizing, specific gasket material, specific transfer line fittings, etc.) 
No Bottom Valves:  There are no bottom valves on the acrylonitrile railcars, and all transfers and unloading is done through a transfer line on the top of the railcar.  This prevents any leaks, drips, or releases from the bottom of the railcar and prevents spills during transfer or unloading operations.  
Cameras:  The acrylonitrile railcar is under surveillance by area cameras that are watched from a main control room.  This is in addition to the field surveillance. 
Fire Water Spray Monitors:  A water spray system that knocks down acrylonitrile vapors to limit and control any vapor release.  
Vendor Railcar Tracking System:  The acrylonitrile 
vendor uses a proprietary railcar tracking system to track the location and condition of each loaded and empty acrylonitrile railcar.  The vendor provides periodic reports from this railcar tracking system to Lyondell.    
Vendor Railcar Mechanical Integrity Program:  The acrylonitrile vendor has a Mechanical Integrity Program for testing, inspection, and maintenance of the acrylonitrile railcars.  This program ensures the structural integrity of the railcar tank and supporting devices such as valves, gaskets, pressure relief devices, hoses, instruments, and coupling systems. 
Surveillance: Railyard operating employees, security personnel, and RESCAR employees make routine unit walk-throughs to make sure the railcars are secure and all safety equipment and systems are operating properly. 
Lyondell Railcar Tracking System (RTMS):  Lyondell uses a proprietary railcar tracking system called Railcar Trip Management System (RTMS).  This railcar tracking system provides daily reports on the lo 
cation, condition, status, product, freight weight, destination, carrier, etc., for acrylonitrile supplier railcars.     
Vendor Emergency Response Systems:  The acrylonitrile vendor has various emergency response systems for responding to any railcar incident nationwide as needed. 
Railroad Transportation Notification and Coordination:  The CSX Railroad Company provides notification and coordination for all acrylonitrile railcars to ensure proper transportation, consignment, movement, and placement.  CSX verifies proper execution of all placement instructions. 
Equipment Design:  Vessels (including shipping containers) and other process equipment are designed according to recognized industry standards and/or governmental requirements. 
Process Safety Information: Chemical hazard, process technology, and equipment information is  documented, maintained up-to-date, and available to operating personnel. 
Process Hazard Analysis: A rigorous practice of reviewing new processes or changes to exi 
sting processes at the design stage to identify and mitigate potential safety, health, and environmental issues before the process is installed and operated.  Scheduled process hazard/risk reviews are conducted to revalidate initial process hazard reviews on a periodic basis.  Process hazard analyses are conducted every five years to identify major process hazard scenarios and to recommend corrective action(s) needed to prevent their occurrence. 
Episodic Risk Management System:  Periodic reviews are conducted to identify hazards which could have significant community impact and to recommend corrective action(s) needed to prevent their occurrence.  These reviews utilize advanced quantitative risk assessment techniques. 
Operational Safety Standards: A company sponsored operational safety program that meets OSHA Process Safety requirements.  Design requirements for active and passive mitigation controls used to prevent major process hazards are documented in the operational safety standar 
ds. 
Operating Procedures:  Operating procedures provide detail on how to safely operate a process and are maintained up-to-date.  All operating procedures are based on process hazard/risk reviews. 
Weighmaster Training/Certification:  A formal training, testing and certification program that ensures proper skill and knowledge prior to independently handling the railcars.  This program requires weighmasters to be trained to inspect, load and unload railcars.  
Technical Staff Training and Support:  Trained technical staff employees are available 24 hours a day to support operations. 
Mechanical Integrity Program:  Vessels (including shipping containers) and other process equipment are periodically tested and inspected to ensure safe operation of process equipment, following recognized standards and/or government requirements.  This program includes testing, inspection and maintenance of critical equipment, including pressure relief devices, hoses, piping, instruments, and shutdown systems. 
 
Material Analysis: Analysis of key chemical raw materials to ensure they meet specifications prior to charging into the process reactor.   Lyondell obtains a Certificate of Analysis from the supplier for all raw material  shipments. 
Quality Assurance:  The plant has a system to ensure that purchased equipment and materials meet established engineering standards and specifications.  
Management of Change:  The plant has a management system to ensure that modified facilities and processes are safe for operation. Design and pre-startup safety reviews are conducted for facility or process changes before the changes are implemented.    
Pre-Startup Safety Reviews:  Reviews are conducted just prior to startup to ensure that modified facilities and processes are safe for operation. 
Incident Investigation:  The plant has a program to ensure accidents, incidents, and near miss events are properly investigated to determine the Root Cause(s) and Contributing Cause(s), and to implement corrective a 
ction(s) that are needed to prevent recurrence. 
Employee Participation:  The plant has a program to involve employees in prevention program elements. 
Permits:  The plant uses a variety of work permits to control those activities that represent work outside of regular plant operations.  These include Lockout/Tagout, Hot Work, Line Breaking and Confined Space Entry permits.  Employees are involved in designing, implementing and following the permits.   
7 Lockout/Tagout - Isolation of equipment to be serviced from energy sources.  This prevents chemical releases and injuries to workers from unexpected energization, start-up, or release of stored energy. 
7 Hot Work - Protects employees and property by preventing fires and explosions.  It ensures, among other things, that no flammable materials are present when an open spark or flame may be present for maintenance activities. The plant has a procedure to ensure that welding, cutting and brazing are safely performed in areas where flammable  
or combustible material may be present. 
7 Line Breaking - Requires isolation and draining of lines to be opened.  It details required personal protective equipment based on the chemical contained in the line. 
7 Confined Space Entry - System using engineering and administrative controls, along with personal protective equipment, to protect the health and safety of personnel working within confined spaces, such as tanks. 
Contractor Safety Program:  The plant has a program to ensure that contractors are properly trained and perform their work in compliance with safety requirements.  Contractors must meet rigorous safety performance requirements before being allowed to work on process equipment.  Contractor employees and regular plant employees must follow all of the same plant safety procedures and requirements.  
Compliance Audits:  Periodic corporate-led and plant-led audits are conducted to ensure that process operations comply with governmental, Lyondell and Union Carbide requirements. 
 
Emergency Procedures:  Plant and process specific emergency response procedures and  training to ensure proper response and notification in the event of a release. 
Manufacturing Excellence Standards: Rigorous corporate standards that we follow to ensure that we operate our facilities in a safe and environmentally sound manner.  Our compliance to these standards is routinely audited by corporate experts.  We have Manufacturing Excellence Standards in the following areas: Environmental, Health and Safety; Technical; Operations; Maintenance; Transportation and Storage; Quality; and Purchasing.  Manufacturing Excellence is Lyondell's comprehensive program to ensure that all the elements listed above are implemented and maintained at every Lyondell facility.  This program includes accountabilities for timely and proper implementation of the program elements. 
 
These general prevention elements and the chemical specific steps discussed in the previous section are parts of an overall manageme 
nt system to prevent accidental chemical releases.  Our company and our employees are committed to the standards that these management systems set.  We have specific accountabilities and controls to ensure that we are meeting our own high standards for accident prevention. 
 
 
V. Five-Year Accident History 
In the last five years there has not been an accident or incident involving an EPA RMP chemical stored by Lyondell at the Union Carbide Massey Railyard that resulted in an on-site death, injury, or property damage; or a known off-site death, injury, evacuation, shelter-in-place, property damage, or environmental damage.  
 
 
VI. Emergency Response Program 
The Union Carbide South Charleston Plant provides emergency response services to the Union Carbide Massey Railyard.  Lyondell has a contract with Union Carbide to obtain emergency response services from the Union Carbide Emergency Response Team at the South Charleston Plant, and the Union Carbide Emergency Operations Center (EOC).  The  
South Charleston Plant maintains a highly trained emergency response team to provide safe and appropriate response to any type of plant emergency and hazardous materials incident.  It also participates in local fire and industrial mutual aid systems through the Kanawha Putnam Emergency Planning Committee (KPEPC).     
 
The South Charleston Plant, which provides emergency response services to the Union Carbide Massey Railyard, maintains a written emergency response program to protect worker and public safety, as well as the environment.  The South Charleston Plant emergency response program includes all of the details from the Massey Railyard , and provisions to handle the hazards at the Massey Railyard.  The program consists of procedures for responding to releases of hazardous substances, including the possibility of a fire or explosion if a flammable substance is accidentally released.  The procedures address all aspects of emergency response including: 
7 Proper first-aid and medical  
treatment for exposures  
7 Evacuation plans and accounting for personnel after an evacuation 
7 Notification of local emergency response agencies and the public if a release occurs 
7 Post-incident cleanup and decontamination requirements, and 
7 Inspecting, testing, maintaining, and using emergency response equipment. 
The emergency response program is updated when necessary based on modifications made to facility processes. 
 
The South Charleston Plant maintains a trained emergency squad to handle fires, explosions, toxic vapor releases, spills, and medical emergencies.   The plant emergency squad trains and drills with local emergency responders to enhance their skills and tactics for responding to an accidental chemical release.   Critiques are held on drills and actual events.  In addition to the plant emergency squad, Union Carbide staffs a Hazardous Emergency Leak Prevention (HELP) team  in the Kanawha Valley that responds to accidental releases within the Massey Railyard and from tr 
ansportation equipment throughout the continental United States.   
 
The emergency response program provides the essential planning and training for effectively protecting workers, the public, and the environment during emergency situations.  Detailed emergency response plans are developed and coordinated with the Kanawha Putnam Emergency Planning Committee and the community. 
 
 
VII. Planned Changes to Improve Safety 
The following is a list of improvements that we are planning to implement at the facility to help prevent and/or better respond to accidental chemical releases: 
7 Continue use and implementation of the Apollo Root Cause Analysis problem solving technique to investigate incidents, to identify causes of process problems, and to develop  effective solutions to prevent their recurrence. 
7 Continue use of Acrylonitrile suppliers with dedicated railcars, Vendor Railcar Tracking Systems, Vendor Emergency Response Systems, and Vendor Railcar Mechanical Integrity Programs.   
7 Upgrad 
e to emergency response computer database to improve ability to calculate release quantities and to increase reference data to improve emergency response capability
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